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Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes

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1 A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences
10.1070/RCR4525
Published 30 November 2014
Communication , Volume 84, Issue 9, 917-951
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Budnikova Y. H., Sinyashin O. G. Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes // Russian Chemical Reviews. 2015. Vol. 84. No. 9. pp. 917-951.
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Budnikova Y. H., Sinyashin O. G. Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes // Russian Chemical Reviews. 2015. Vol. 84. No. 9. pp. 917-951.
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TY - JOUR
DO - 10.1070/RCR4525
UR - https://rcr.colab.ws/publications/10.1070/RCR4525
TI - Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes
T2 - Russian Chemical Reviews
AU - Budnikova, Yulia Hermanovna
AU - Sinyashin, Oleg Gerol'dovich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 917-951
IS - 9
VL - 84
ER -
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@article{2015_Budnikova,
author = {Yulia Hermanovna Budnikova and Oleg Gerol'dovich Sinyashin},
title = {Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4525},
number = {9},
pages = {917--951},
doi = {10.1070/RCR4525}
}
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Budnikova, Yulia Hermanovna, and Oleg Gerol'dovich Sinyashin. “Phosphorylation of C--H bonds of aromatic compounds using metals and metal complexes.” Russian Chemical Reviews, vol. 84, no. 9, Nov. 2015, pp. 917-951. https://rcr.colab.ws/publications/10.1070/RCR4525.
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Abstract

Key achievements and current trends in the development of methods for phosphorylation of aromatic C--H bonds catalyzed by metal salts and complexes are considered. The most important and promising approaches of the last decade, including those concerning the synthesis and properties of arylphosphonates, are distinguished. Methods for the introduction of a phosphonate group into non-activated and functionally substituted aromatic compounds and heteroaromatic molecules and phosphorylation--cyclization reactions involving acetylenes, 2-isocyanobiphenyls and alkynoates are analyzed. The possibilities of ligand-directed phosphorylation of compounds with aromatic C--H bonds and presumed mechanisms and intermediates in the C--P bond formation reactions are considered. The potential of this extensively developing research trend in organic and organoelement chemistry is highlighted.

The bibliography includes 263~references.

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