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$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis

Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
, 
S V Kochetkov 1
S V Kochetkov
1 N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
10.1070/RCR4562
Published 30 November 2014
Communication , Volume 84, Issue 11, 1077-1099
32
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Zlotin S. G., Kochetkov S. V. $C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1077-1099.
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Zlotin S. G., Kochetkov S. V. $C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1077-1099.
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TY - JOUR
DO - 10.1070/RCR4562
UR - https://rcr.colab.ws/publications/10.1070/RCR4562
TI - $C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis
T2 - Russian Chemical Reviews
AU - Zlotin, Sergei Grigorievich
AU - Kochetkov, S V
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1077-1099
IS - 11
VL - 84
ER -
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@article{2015_Zlotin,
author = {Sergei Grigorievich Zlotin and S V Kochetkov},
title = {$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4562},
number = {11},
pages = {1077--1099},
doi = {10.1070/RCR4562}
}
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Zlotin, Sergei Grigorievich, and S V Kochetkov. “$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis.” Russian Chemical Reviews, vol. 84, no. 11, Nov. 2015, pp. 1077-1099. https://rcr.colab.ws/publications/10.1070/RCR4562.
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Abstract

The review is devoted to the application of $C_2$-symmetric diamines and their derivatives as organocatalysts for asymmetric reactions (aldol, Michael, Mannich, Diels--Alder reactions, desymmetrization, allylation, {\it etc}.). Amino acid derivatives, di- and polyamides (sulfamides), bisureas, bisthioureas, bisamidines and bisguanidines are considered. Significant attention is given to the effect of the catalyst structure on the mechanism of catalytic action. Successful applications of such catalysts in enantioselective synthesis of chiral biologically active compounds are summarized.

The bibliography includes 181 references.

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