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Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

Mariya Vladimirovna Edeleva 1, 2
Mariya Vladimirovna Edeleva
, 
Sylvain R.A. Marque 2, 3
Sylvain R.A. Marque
, 
Elena Grigor'evna Bagryanskaya 1, 2
Elena Grigor'evna Bagryanskaya
1 Novosibirsk State University
2 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of Russian Academy of Sciences
3 Aix-Marseille University, National Center for Scientific Research, Institute of Radical Chemistry, France
10.1070/RCR4765
Published 30 November 2017
Review , RCR4765, Volume 87, Issue 4, 328-349
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Edeleva M. V., Marque S. R., Bagryanskaya E. G. Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization // Russian Chemical Reviews. 2017. Vol. 87. No. 4. pp. 328-349.
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Edeleva M. V., Marque S. R., Bagryanskaya E. G. Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization // Russian Chemical Reviews. 2017. Vol. 87. No. 4. pp. 328-349.
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TY - JOUR
DO - 10.1070/RCR4765
UR - https://rcr.colab.ws/publications/10.1070/RCR4765
TI - Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization
T2 - Russian Chemical Reviews
AU - Edeleva, Mariya Vladimirovna
AU - Marque, Sylvain R.A.
AU - Bagryanskaya, Elena Grigor'evna
PY - 2017
DA - 2017/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 328-349
IS - 4
VL - 87
ER -
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@article{2017_Edeleva,
author = {Mariya Vladimirovna Edeleva and Sylvain R.A. Marque and Elena Grigor'evna Bagryanskaya},
title = {Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization},
journal = {Russian Chemical Reviews},
year = {2017},
volume = {87},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4765},
number = {4},
pages = {328--349},
doi = {10.1070/RCR4765}
}
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Edeleva, Mariya Vladimirovna, et al. “Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization.” Russian Chemical Reviews, vol. 87, no. 4, Nov. 2017, pp. 328-349. https://rcr.colab.ws/publications/10.1070/RCR4765.
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Abstract

Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular-weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.

The bibliography includes 154 references.

Funders

Russian Foundation for Basic Research
15-03-05250
Russian Science Foundation
15-13-20020

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