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Molecular design of stable diarylnitroxides

Tatyana Vladimirovna Magdesieva 1
Tatyana Vladimirovna Magdesieva
, 
Oleg Aleksandrovich Levitskiy 1
Oleg Aleksandrovich Levitskiy
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RCR4769
Published 30 November 2017
Review , RCR4769, Volume 87, Issue 7, 707-725
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Magdesieva T. V., Levitskiy O. A. Molecular design of stable diarylnitroxides // Russian Chemical Reviews. 2017. Vol. 87. No. 7. pp. 707-725.
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Magdesieva T. V., Levitskiy O. A. Molecular design of stable diarylnitroxides // Russian Chemical Reviews. 2017. Vol. 87. No. 7. pp. 707-725.
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TY - JOUR
DO - 10.1070/RCR4769
UR - https://rcr.colab.ws/publications/10.1070/RCR4769
TI - Molecular design of stable diarylnitroxides
T2 - Russian Chemical Reviews
AU - Magdesieva, Tatyana Vladimirovna
AU - Levitskiy, Oleg Aleksandrovich
PY - 2017
DA - 2017/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 707-725
IS - 7
VL - 87
ER -
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@article{2017_Magdesieva,
author = {Tatyana Vladimirovna Magdesieva and Oleg Aleksandrovich Levitskiy},
title = {Molecular design of stable diarylnitroxides},
journal = {Russian Chemical Reviews},
year = {2017},
volume = {87},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4769},
number = {7},
pages = {707--725},
doi = {10.1070/RCR4769}
}
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Magdesieva, Tatyana Vladimirovna, and Oleg Aleksandrovich Levitskiy. “Molecular design of stable diarylnitroxides.” Russian Chemical Reviews, vol. 87, no. 7, Nov. 2017, pp. 707-725. https://rcr.colab.ws/publications/10.1070/RCR4769.
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Abstract

The review is devoted to diarylnitroxides, which constitute an important type of organic radicals. These compounds are much less investigated than their alkyl counterparts. Meanwhile, they are of great interest, since they provide extensive opportunities for targeted structural modification and control of electronic properties of a molecule for a particular practical application. The existing trends of molecular design of stable diarylnitroxides and general approaches to their synthesis are discussed. Structural details and spin density distribution in diarylnitroxides are considered. Factors determining the stability of both the diarylnitroxide radicals and their oxidized and reduced forms and the redox properties of this class of organic radicals are addressed.

The bibliography includes 128 references.

Funders

Russian Science Foundation
16-13-10282

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