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Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes

Vladimir Anatol'evich D'yakonov 1
Vladimir Anatol'evich D'yakonov
, 
Gulnara Nazifovna Kadikova 1
Gulnara Nazifovna Kadikova
, 
1 Institute of Petrochemistry and Catalysis of RAS, Ufa
10.1070/RCR4793
Published 30 November 2017
Review , RCR4793, Volume 87, Issue 8, 797-820
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D'yakonov V. A., Kadikova G. N., Dzhemilev U. M. Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes // Russian Chemical Reviews. 2017. Vol. 87. No. 8. pp. 797-820.
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D'yakonov V. A., Kadikova G. N., Dzhemilev U. M. Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes // Russian Chemical Reviews. 2017. Vol. 87. No. 8. pp. 797-820.
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TY - JOUR
DO - 10.1070/RCR4793
UR - https://rcr.colab.ws/publications/10.1070/RCR4793
TI - Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes
T2 - Russian Chemical Reviews
AU - D'yakonov, Vladimir Anatol'evich
AU - Kadikova, Gulnara Nazifovna
AU - Dzhemilev, Usein Memetovich
PY - 2017
DA - 2017/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 797-820
IS - 8
VL - 87
ER -
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@article{2017_D'yakonov,
author = {Vladimir Anatol'evich D'yakonov and Gulnara Nazifovna Kadikova and Usein Memetovich Dzhemilev},
title = {Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes},
journal = {Russian Chemical Reviews},
year = {2017},
volume = {87},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4793},
number = {8},
pages = {797--820},
doi = {10.1070/RCR4793}
}
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D'yakonov, Vladimir Anatol'evich, et al. “Transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes.” Russian Chemical Reviews, vol. 87, no. 8, Nov. 2017, pp. 797-820. https://rcr.colab.ws/publications/10.1070/RCR4793.
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Abstract

The current review summarizes the published data on transition metal complex-mediated chemistry of 1,3,5-cycloheptatrienes. It addresses homodimerization of cycloheptatrienes and cyclocodimerization of the latter with alkenes, dienes and alkynes in the presence of transition metal complexes that occur via [2$\pi$+2$\pi$], [3$\pi$+2$\pi$], [6$\pi$+2$\pi$], [6$\pi$+4$\pi$] and [6$\pi$+2$\pi$+2$\pi$] cycloadditions. Special attention is given to the application of these reactions in the synthesis of valuable strained bi-, tri- and polycyclic compounds and for the development of methods of stereoselective synthesis of natural products.

The bibliography includes 91 references.

Funders

Russian Science Foundation
17-73-10096

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