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Catalytic asymmetric oxidations using molecular oxygen

Roman Viktorovich Ottenbacher 1, 2
Roman Viktorovich Ottenbacher
, 
Evgenii Pavlovich Talsi 1, 2
Evgenii Pavlovich Talsi
, 
Konstantin Petrovich Bryliakov 1, 2
Konstantin Petrovich Bryliakov
1 Novosibirsk State University
2 Boreskov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RCR4825
Published 30 November 2017
Review , RCR4825, Volume 87, Issue 9, 821-830
17
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Ottenbacher R. V., Talsi E. P., Bryliakov K. P. Catalytic asymmetric oxidations using molecular oxygen // Russian Chemical Reviews. 2017. Vol. 87. No. 9. pp. 821-830.
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Ottenbacher R. V., Talsi E. P., Bryliakov K. P. Catalytic asymmetric oxidations using molecular oxygen // Russian Chemical Reviews. 2017. Vol. 87. No. 9. pp. 821-830.
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TY - JOUR
DO - 10.1070/RCR4825
UR - https://rcr.colab.ws/publications/10.1070/RCR4825
TI - Catalytic asymmetric oxidations using molecular oxygen
T2 - Russian Chemical Reviews
AU - Ottenbacher, Roman Viktorovich
AU - Talsi, Evgenii Pavlovich
AU - Bryliakov, Konstantin Petrovich
PY - 2017
DA - 2017/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 821-830
IS - 9
VL - 87
ER -
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@article{2017_Ottenbacher,
author = {Roman Viktorovich Ottenbacher and Evgenii Pavlovich Talsi and Konstantin Petrovich Bryliakov},
title = {Catalytic asymmetric oxidations using molecular oxygen},
journal = {Russian Chemical Reviews},
year = {2017},
volume = {87},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4825},
number = {9},
pages = {821--830},
doi = {10.1070/RCR4825}
}
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Ottenbacher, Roman Viktorovich, et al. “Catalytic asymmetric oxidations using molecular oxygen.” Russian Chemical Reviews, vol. 87, no. 9, Nov. 2017, pp. 821-830. https://rcr.colab.ws/publications/10.1070/RCR4825.
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Abstract

Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new

$\mathrm{C}$ -- $\mathrm{O}$ bonds, \textit{i.e}. oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance.

The bibliography includes 41 references.

Funders

Russian Foundation for Basic Research
16-29-10666

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