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Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements

Alena Andreevna Starikova 1
Alena Andreevna Starikova
, 
1 Institute of Physical and Organic Chemistry at Southern Federal University
10.1070/RCR4837
Published 30 November 2017
Review , RCR4837, Volume 87, Issue 11, 1049-1079
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Starikova A. A., Minkin V. I. Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements // Russian Chemical Reviews. 2017. Vol. 87. No. 11. pp. 1049-1079.
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Starikova A. A., Minkin V. I. Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements // Russian Chemical Reviews. 2017. Vol. 87. No. 11. pp. 1049-1079.
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TY - JOUR
DO - 10.1070/RCR4837
UR - https://rcr.colab.ws/publications/10.1070/RCR4837
TI - Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements
T2 - Russian Chemical Reviews
AU - Starikova, Alena Andreevna
AU - Minkin, Vladimir Isaakovich
PY - 2017
DA - 2017/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1049-1079
IS - 11
VL - 87
ER -
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@article{2017_Starikova,
author = {Alena Andreevna Starikova and Vladimir Isaakovich Minkin},
title = {Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements},
journal = {Russian Chemical Reviews},
year = {2017},
volume = {87},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4837},
number = {11},
pages = {1049--1079},
doi = {10.1070/RCR4837}
}
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Starikova, Alena Andreevna, and Vladimir Isaakovich Minkin. “Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements.” Russian Chemical Reviews, vol. 87, no. 11, Nov. 2017, pp. 1049-1079. https://rcr.colab.ws/publications/10.1070/RCR4837.
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Keywords

adducts of metal complexes
magnetic properties
quantum-chemical modeling
redox-active ligands
spin-crossover
valence tautomerism

Abstract

The currently available literature data on the synthesis, molecular and electronic structure of mixed-ligand complexes (adducts) of transition metals (chromium, manganese, iron, cobalt, ruthenium) with organic redox-active ligands are systematically considered for the first time. The possibility of manifestation of magnetic bistability by adducts of tetracoordinate CoII and FeII complexes and the potential for their application as molecular switches are studied in detail by means of quantum chemical modelling of thermally initiated rearrangements controlled by the spin crossover and valence tautomerism mechanisms. Special attention is given to dinuclear adducts of CoII and FeII complexes with linearly bonded and polycyclic di-o-quinones and their imines, which can operate as thermally switchable elements of quantum computers suitable for practical implementation of two-qubit gates.

The bibliography includes 183 references.

Funders

Russian Science Foundation
14-13-00573
Ministry of Education and Science of the Russian Federation
1.5056.2017/6.7

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