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Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks

Vladimir Valentinovich Arslanov 1
Vladimir Valentinovich Arslanov
, 
Maria Aleksandrovna Kalinina 1
Maria Aleksandrovna Kalinina
, 
Elizaveta Viktorovna Ermakova 1
Elizaveta Viktorovna Ermakova
, 
Oleg Arkad'evich Raitman 1
Oleg Arkad'evich Raitman
,  , 
Oleg Evgen'evich Aksyutin 3
Oleg Evgen'evich Aksyutin
, 
Aleksander Gavrilovich Ishkov 3
Aleksander Gavrilovich Ishkov
, 
Vladimir Aleksandrovich Grachev 1
Vladimir Aleksandrovich Grachev
, 
1 Institute of Physical Chemistry and Electro Chemistry, Russian Academy of Sciences, Moscow
2 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
3 OAO "Gazprom", Moscow
10.1070/RCR4878
Published 30 November 2018
Review , RCR4878, Volume 88, Issue 8, 775-799
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Arslanov V. V. et al. Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks // Russian Chemical Reviews. 2018. Vol. 88. No. 8. pp. 775-799.
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Arslanov V. V., Kalinina M. A., Ermakova E. V., Raitman O. A., Gorbunova Y. G., Aksyutin O. E., Ishkov A. G., Grachev V. A., Tsivadze A. Y. Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks // Russian Chemical Reviews. 2018. Vol. 88. No. 8. pp. 775-799.
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TY - JOUR
DO - 10.1070/RCR4878
UR - https://rcr.colab.ws/publications/10.1070/RCR4878
TI - Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks
T2 - Russian Chemical Reviews
AU - Arslanov, Vladimir Valentinovich
AU - Kalinina, Maria Aleksandrovna
AU - Ermakova, Elizaveta Viktorovna
AU - Raitman, Oleg Arkad'evich
AU - Gorbunova, Yulia Germanovna
AU - Aksyutin, Oleg Evgen'evich
AU - Ishkov, Aleksander Gavrilovich
AU - Grachev, Vladimir Aleksandrovich
AU - Tsivadze, Aslan Yusupovich
PY - 2018
DA - 2018/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 775-799
IS - 8
VL - 88
ER -
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@article{2018_Arslanov,
author = {Vladimir Valentinovich Arslanov and Maria Aleksandrovna Kalinina and Elizaveta Viktorovna Ermakova and Oleg Arkad'evich Raitman and Yulia Germanovna Gorbunova and Oleg Evgen'evich Aksyutin and Aleksander Gavrilovich Ishkov and Vladimir Aleksandrovich Grachev and Aslan Yusupovich Tsivadze},
title = {Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks},
journal = {Russian Chemical Reviews},
year = {2018},
volume = {88},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4878},
number = {8},
pages = {775--799},
doi = {10.1070/RCR4878}
}
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Arslanov, Vladimir Valentinovich, et al. “Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks.” Russian Chemical Reviews, vol. 88, no. 8, Nov. 2018, pp. 775-799. https://rcr.colab.ws/publications/10.1070/RCR4878.
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Abstract

Domestic and foreign literature on methods for obtaining graphene and its derivatives [graphene oxide (GO) and reduced GO] as representatives of the family of 2D layered materials is analyzed. Particular attention is paid to GO. Great potential of post-synthetic modification as well as unique properties of the material and its derivatives make them promising for a variety of applications including biomedicine, ecology, optoelectronics, \textit{etc}. Chemical and physical methods for the reduction of GO to obtain graphene-like materials similar in structure and properties to pure graphene obtained by direct mechanical cleavage are considered. Functionalization strategies of graphene materials are discussed. The preparation of hydro- and organogels as well as Pickering emulsions from graphene derivatives as precursors of porous monoliths are considered. The formation of aerogels based on graphene materials and methane adsorption on these porous structures are discussed. Basic information about hybrid materials containing graphene derivatives and metal-organic frameworks is given and their adsorption characteristics with respect to methane are evaluated. Covalent and noncovalent interactions in graphene--porphyrin hybrids are considered from the standpoint of formation of porphyrin architectures on the surface of graphene materials. Examples of the use of porphyrin--graphene composite materials in photo- and electrocatalysis, fuel cells and gas separation membranes are given. The bibliography includes 243 references.

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