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Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure

Konstantin Vasil'evich Pochivalov 1
Konstantin Vasil'evich Pochivalov
, 
Andrey Viktorovich Basko 1
Andrey Viktorovich Basko
, 
Yaroslav Viktorovich Kudryavtsev 2
Yaroslav Viktorovich Kudryavtsev
1 G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo
2 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
10.1070/RCR4896
Published 30 November 2019
Review , RCR4896, Volume 89, Issue 3, 311-338
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Pochivalov K. V., Basko A. V., Kudryavtsev Y. V. Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure // Russian Chemical Reviews. 2019. Vol. 89. No. 3. pp. 311-338.
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Pochivalov K. V., Basko A. V., Kudryavtsev Y. V. Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure // Russian Chemical Reviews. 2019. Vol. 89. No. 3. pp. 311-338.
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TY - JOUR
DO - 10.1070/RCR4896
UR - https://rcr.colab.ws/publications/10.1070/RCR4896
TI - Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure
T2 - Russian Chemical Reviews
AU - Pochivalov, Konstantin Vasil'evich
AU - Basko, Andrey Viktorovich
AU - Kudryavtsev, Yaroslav Viktorovich
PY - 2019
DA - 2019/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 311-338
IS - 3
VL - 89
ER -
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@article{2019_Pochivalov,
author = {Konstantin Vasil'evich Pochivalov and Andrey Viktorovich Basko and Yaroslav Viktorovich Kudryavtsev},
title = {Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {89},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4896},
number = {3},
pages = {311--338},
doi = {10.1070/RCR4896}
}
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Pochivalov, Konstantin Vasil'evich, et al. “Binary mixtures of semicrystalline polymers with low-molecular-mass compounds: thermal behaviour and phase structure.” Russian Chemical Reviews, vol. 89, no. 3, Nov. 2019, pp. 311-338. https://rcr.colab.ws/publications/10.1070/RCR4896.
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Abstract

The results of phase equilibrium studies in mixtures of semicrystalline polymers with low-molecular-mass compounds are summarized and analyzed. A new classification of phase diagrams for such mixtures is proposed. Alternative points of view on the phase composition of semicrystalline polymers are presented. The phase structure evolution during the thermally induced phase separation of mixtures is monitored and the morphology of the forming capillary porous bodies as precursors of polymeric membranes is described. The general regularities concerning the influence of the nature of mixture components, polymer molecular mass, temperature scanning rate and other factors on the topology of phase diagrams are considered. Experimental methods used to construct the phase diagrams of mixtures and to study features of their phase structure are compared.

The bibliography includes 203 references.

Funders

Ministry of Education and Science of the Russian Federation
01201260483

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