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Organophosphorus chemistry based on elemental phosphorus: advances and horizons

Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
1 A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Published 30 November 2019
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Gusarova N. K., Trofimov B. A. Organophosphorus chemistry based on elemental phosphorus: advances and horizons // Russian Chemical Reviews. 2019. Vol. 89. No. 2. pp. 225-249.
GOST all authors (up to 50)
Gusarova N. K., Trofimov B. A. Organophosphorus chemistry based on elemental phosphorus: advances and horizons // Russian Chemical Reviews. 2019. Vol. 89. No. 2. pp. 225-249.
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TY - JOUR
DO - 10.1070/RCR4903
UR - https://rcr.colab.ws/publications/10.1070/RCR4903
TI - Organophosphorus chemistry based on elemental phosphorus: advances and horizons
T2 - Russian Chemical Reviews
AU - Gusarova, Nina Kuzminichna
AU - Trofimov, Boris Aleksandrovich
PY - 2019
DA - 2019/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 225-249
IS - 2
VL - 89
ER -
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@article{2019_Gusarova,
author = {Nina Kuzminichna Gusarova and Boris Aleksandrovich Trofimov},
title = {Organophosphorus chemistry based on elemental phosphorus: advances and horizons},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {89},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4903},
number = {2},
pages = {225--249},
doi = {10.1070/RCR4903}
}
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Cite this
MLA
Gusarova, Nina Kuzminichna, and Boris Aleksandrovich Trofimov. “Organophosphorus chemistry based on elemental phosphorus: advances and horizons.” Russian Chemical Reviews, vol. 89, no. 2, Nov. 2019, pp. 225-249. https://rcr.colab.ws/publications/10.1070/RCR4903.
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Keywords

electrochemistry
elemental (red and white) phosphorus
phosphination
phosphine chalcogenides
phosphines
phosphinic acids
phosphinylation
superbases

Abstract

The results of studies on the application of elemental phosphorus for the synthesis of important organophosphorus compounds are surveyed and summarized. Currently, this trend represents a synthetically, environmentally and technologically attractive alternative to classical organophosphorus chemistry based on toxic and corrosive phosphorus chlorides. Direct phosphination and phosphinylation of organic compounds with elemental phosphorus (discussed in the first part of the review) basically extend the range of available phosphines, phosphine chalcogenides and phosphinic acids and provides further development of their synthetic potential (discussed in the second part of the review). It is shown that the breakthrough in this area is largely due to the discovery of reactions of elemental phosphorus (white and red) with various electrophiles in superbasic suspensions and emulsions derived from alkali metal hydroxides and to the development of electrochemical, electrocatalytic and catalytic activation of white phosphorus.

The bibliography includes 299 references.

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