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Recent advances in catalytic asymmetric dihydroxylation of olefins

Roman Viktorovich Ottenbacher 1, 2
Roman Viktorovich Ottenbacher
, 
Evgenii Pavlovich Talsi 1, 2
Evgenii Pavlovich Talsi
, 
Konstantin Petrovich Bryliakov 1, 2
Konstantin Petrovich Bryliakov
1 Novosibirsk State University
2 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RCR4904
Published 30 November 2018
Review , RCR4904, Volume 88, Issue 11, 1094-1103
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Ottenbacher R. V., Talsi E. P., Bryliakov K. P. Recent advances in catalytic asymmetric dihydroxylation of olefins // Russian Chemical Reviews. 2018. Vol. 88. No. 11. pp. 1094-1103.
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Ottenbacher R. V., Talsi E. P., Bryliakov K. P. Recent advances in catalytic asymmetric dihydroxylation of olefins // Russian Chemical Reviews. 2018. Vol. 88. No. 11. pp. 1094-1103.
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TY - JOUR
DO - 10.1070/RCR4904
UR - https://rcr.colab.ws/publications/10.1070/RCR4904
TI - Recent advances in catalytic asymmetric dihydroxylation of olefins
T2 - Russian Chemical Reviews
AU - Ottenbacher, Roman Viktorovich
AU - Talsi, Evgenii Pavlovich
AU - Bryliakov, Konstantin Petrovich
PY - 2018
DA - 2018/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1094-1103
IS - 11
VL - 88
ER -
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@article{2018_Ottenbacher,
author = {Roman Viktorovich Ottenbacher and Evgenii Pavlovich Talsi and Konstantin Petrovich Bryliakov},
title = {Recent advances in catalytic asymmetric dihydroxylation of olefins},
journal = {Russian Chemical Reviews},
year = {2018},
volume = {88},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4904},
number = {11},
pages = {1094--1103},
doi = {10.1070/RCR4904}
}
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Ottenbacher, Roman Viktorovich, et al. “Recent advances in catalytic asymmetric dihydroxylation of olefins.” Russian Chemical Reviews, vol. 88, no. 11, Nov. 2018, pp. 1094-1103. https://rcr.colab.ws/publications/10.1070/RCR4904.
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Abstract

Asymmetric dihydroxylation of olefinic groups is an extremely important synthetic transformation which has been widely utilized to obtain optically pure pharmaceuticals and other fine chemical products. In recent years,catalyst systems for the asymmetric C=C dihydroxylations have attracted significant interest, the major research efforts being focused on designing environmentally benign catalyst systems. This mini-review summarizes recent progress in the field, surveying both novel, less toxic modifications of the classical osmium-based catalysts, and the highly efficient and enantioselective non-osmium catalyst systems.

The bibliography includes 50 references.

Funders

Russian Foundation for Basic Research
16-29-10666
Ministry of Education and Science of the Russian Federation
AAAA-A17-117041710080-4

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