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Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I

, 
Carmen Nájera 2
Carmen Nájera
, 
Miguel Yus 2
Miguel Yus
1 Lomonosov Moscow State University, Faculty of Chemistry
2 University of Alicante, Spain
10.1070/RCR4916
Published 30 November 2019
Review , RCR4916, Volume 89, Issue 2, 250-274
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I // Russian Chemical Reviews. 2019. Vol. 89. No. 2. pp. 250-274.
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I // Russian Chemical Reviews. 2019. Vol. 89. No. 2. pp. 250-274.
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TY - JOUR
DO - 10.1070/RCR4916
UR - https://rcr.colab.ws/publications/10.1070/RCR4916
TI - Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I
T2 - Russian Chemical Reviews
AU - Beletskaya, Irina Petrovna
AU - Nájera, Carmen
AU - Yus, Miguel
PY - 2019
DA - 2019/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 250-274
IS - 2
VL - 89
ER -
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@article{2019_Beletskaya,
author = {Irina Petrovna Beletskaya and Carmen Nájera and Miguel Yus},
title = {Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {89},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4916},
number = {2},
pages = {250--274},
doi = {10.1070/RCR4916}
}
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Beletskaya, Irina Petrovna, et al. “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part~I.” Russian Chemical Reviews, vol. 89, no. 2, Nov. 2019, pp. 250-274. https://rcr.colab.ws/publications/10.1070/RCR4916.
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Abstract

The review presents state-of-the-art data on the influence of catalysts (mainly transition metal complexes) on the regioselectivity of a number of reactions. The most important addition reactions to unsaturated bonds are considered, in particular, hydroformylation, hydrosilylation, hydroboration and hydroxy-, alkoxy- and aminocarbonylation, which give predominantly one product. Particular attention is given to reactions with divergent regioselectivity. The reaction conditions, the structures of metal complexes and the ligands involved are indicated and, in some cases, the reaction mechanism is discussed. Examples of industrial processes using homogeneous catalysis are given.

The bibliography includes 203 references.

Funders

Russian Science Foundation
19-13-00223

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