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Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination

, 
Carmen Nájera 2
Carmen Nájera
, 
Miguel Yus 2
Miguel Yus
1 Lomonosov Moscow State University, Faculty of Chemistry
2 University of Alicante, Spain
10.1070/RCR4953
Published 30 November 2019
Review , RCR4953, Volume 89, Issue 10, 1074-1114
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination // Russian Chemical Reviews. 2019. Vol. 89. No. 10. pp. 1074-1114.
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Beletskaya I. P., Nájera C., Yus M. Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination // Russian Chemical Reviews. 2019. Vol. 89. No. 10. pp. 1074-1114.
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TY - JOUR
DO - 10.1070/RCR4953
UR - https://rcr.colab.ws/publications/10.1070/RCR4953
TI - Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination
T2 - Russian Chemical Reviews
AU - Beletskaya, Irina Petrovna
AU - Nájera, Carmen
AU - Yus, Miguel
PY - 2019
DA - 2019/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1074-1114
IS - 10
VL - 89
ER -
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@article{2019_Beletskaya,
author = {Irina Petrovna Beletskaya and Carmen Nájera and Miguel Yus},
title = {Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {89},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4953},
number = {10},
pages = {1074--1114},
doi = {10.1070/RCR4953}
}
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Beletskaya, Irina Petrovna, et al. “Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination.” Russian Chemical Reviews, vol. 89, no. 10, Nov. 2019, pp. 1074-1114. https://rcr.colab.ws/publications/10.1070/RCR4953.
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Keywords

alkenes
alkynes
allenes
catalysis
dienes
Hydroamidation
Hydroamination
regioselectivity

Abstract

This review continues consideration of the regioselectivity problem in the catalyzed hydrofunctionalization of unsaturated organic compounds and addresses hydroamination of unsaturated hydrocarbons. Particular parts of the review deal with reactions of alkenes, alkynes, allenes and dienes. It is shown that the selectivity of hydroamination depends on the natures of the reactants and the catalyst. Conditions of the reactions are described; in some cases, reaction mechanisms are discussed. Reactions for which divergent regioselectivity is possible are noted.

The bibliography includes 250 references.

Funders

Russian Science Foundation
19-13-00223

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