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Catalysis by platinum and palladium species confined in the bulk of glass fibre materials

Bair Sydypovich Bal'zhinimaev 1
Bair Sydypovich Bal'zhinimaev
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
10.1070/RCR4958
Published 30 November 2019
Review , RCR4958, Volume 89, Issue 11, 1184-1203
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Bal'zhinimaev B. S. Catalysis by platinum and palladium species confined in the bulk of glass fibre materials // Russian Chemical Reviews. 2019. Vol. 89. No. 11. pp. 1184-1203.
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Bal'zhinimaev B. S. Catalysis by platinum and palladium species confined in the bulk of glass fibre materials // Russian Chemical Reviews. 2019. Vol. 89. No. 11. pp. 1184-1203.
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TY - JOUR
DO - 10.1070/RCR4958
UR - https://rcr.colab.ws/publications/10.1070/RCR4958
TI - Catalysis by platinum and palladium species confined in the bulk of glass fibre materials
T2 - Russian Chemical Reviews
AU - Bal'zhinimaev, Bair Sydypovich
PY - 2019
DA - 2019/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1184-1203
IS - 11
VL - 89
ER -
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@article{2019_Bal'zhinimaev,
author = {Bair Sydypovich Bal'zhinimaev},
title = {Catalysis by platinum and palladium species confined in the bulk of glass fibre materials},
journal = {Russian Chemical Reviews},
year = {2019},
volume = {89},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4958},
number = {11},
pages = {1184--1203},
doi = {10.1070/RCR4958}
}
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Bal'zhinimaev, Bair Sydypovich. “Catalysis by platinum and palladium species confined in the bulk of glass fibre materials.” Russian Chemical Reviews, vol. 89, no. 11, Nov. 2019, pp. 1184-1203. https://rcr.colab.ws/publications/10.1070/RCR4958.
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Keywords

deep oxidation
glass fibers
kinetics
mechanism
Pt and Pd catalysts
selective hydrogenation
turnover frequency
VOC and CVOC

Abstract

The results of studies on the application of silicate glass fibre materials in catalysis are summarized and analyzed. Despite the very low noble metal content, catalysts based on these materials showed exceptionally high activities and selectivities in some catalytic reactions. This is due to specificity of the glassy state, which makes it possible, first, to confine highly dispersed palladium and platinum species in the bulk of glass fibres and, second, selectively absorb polar molecules, thus excluding the undesirable reactions involving non-polar molecules. The size dependences of the complete oxidation of propane and selective hydrogenation of acetylene, the nature of the structure sensitivity of these reactions and the reaction mechanisms are discussed. Ways for improving glass fibre catalyst performance are proposed and examples of the successful application of Pt/glass fibre catalysts for purification of industrial gases from volatile organic compounds are given.

The bibliography includes 175 references.

Funders

Ministry of Education and Science of the Russian Federation
АААА-А17-117041710083-5

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