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Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications

Dmitry Fedorovich Grishin 1
Dmitry Fedorovich Grishin
, 
Ivan Dmitrievich Grishin 1
Ivan Dmitrievich Grishin
1 National Research Lobachevsky State University of Nizhny Novgorod
10.1070/RCR4964
Published 30 November 2020
Review , RCR4964, Volume 90, Issue 2, 231-264
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Grishin D. F., Grishin I. D. Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications // Russian Chemical Reviews. 2020. Vol. 90. No. 2. pp. 231-264.
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Grishin D. F., Grishin I. D. Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications // Russian Chemical Reviews. 2020. Vol. 90. No. 2. pp. 231-264.
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TY - JOUR
DO - 10.1070/RCR4964
UR - https://rcr.colab.ws/publications/10.1070/RCR4964
TI - Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications
T2 - Russian Chemical Reviews
AU - Grishin, Dmitry Fedorovich
AU - Grishin, Ivan Dmitrievich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 231-264
IS - 2
VL - 90
ER -
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@article{2020_Grishin,
author = {Dmitry Fedorovich Grishin and Ivan Dmitrievich Grishin},
title = {Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4964},
number = {2},
pages = {231--264},
doi = {10.1070/RCR4964}
}
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Grishin, Dmitry Fedorovich, and Ivan Dmitrievich Grishin. “Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications.” Russian Chemical Reviews, vol. 90, no. 2, Nov. 2020, pp. 231-264. https://rcr.colab.ws/publications/10.1070/RCR4964.
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Keywords

Atom Transfer Radical Polymerization
Controlled Radical Polymerization
Degenerative Transfer
Metal-Free ATRP
Nitroxide-Mediated Radical Polymerization
Reversible Addition-Fragmentation
Reversible-Deactivated Radical Polymerization

Abstract

Major trends in controlled radical polymerization (CRP) or reversible-deactivation radical polymerization (RDRP), the most efficient method of synthesis of well-defined homo- and copolymers with specified parameters and properties, are critically analyzed. Recent advances associated with the three classical versions of CRP: nitroxide mediated polymerization, reversible addition-fragmentation chain transfer polymerization and atom transfer radical polymerization, are considered. Particular attention is paid to the prospects for the application of photoinitiation and photocatalysis in CRP. This approach, which has been intensively explored recently, brings synthetic methods of polymer chemistry closer to the light-induced processes of macromolecular synthesis occurring in living organisms. Examples are given of practical application of CRP techniques to obtain industrially valuable, high-tech polymeric products.

The bibliography includes 429 references.

Funders

Russian Foundation for Basic Research
19-13-50010

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