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Recent advances in chemistry of high-spin nitrenes

Sergei Viktorovich Chapyshev 1
Sergei Viktorovich Chapyshev
, 
Denis Vladimirovich Korchagin 1
Denis Vladimirovich Korchagin
, 
Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RCR4965
Published 30 November 2020
Review , RCR4965, Volume 90, Issue 1, 39-69
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Chapyshev S. V., Korchagin D. V., Misochko E. Y. Recent advances in chemistry of high-spin nitrenes // Russian Chemical Reviews. 2020. Vol. 90. No. 1. pp. 39-69.
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Chapyshev S. V., Korchagin D. V., Misochko E. Y. Recent advances in chemistry of high-spin nitrenes // Russian Chemical Reviews. 2020. Vol. 90. No. 1. pp. 39-69.
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TY - JOUR
DO - 10.1070/RCR4965
UR - https://rcr.colab.ws/publications/10.1070/RCR4965
TI - Recent advances in chemistry of high-spin nitrenes
T2 - Russian Chemical Reviews
AU - Chapyshev, Sergei Viktorovich
AU - Korchagin, Denis Vladimirovich
AU - Misochko, Evgenii Yakovlevich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 39-69
IS - 1
VL - 90
ER -
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@article{2020_Chapyshev,
author = {Sergei Viktorovich Chapyshev and Denis Vladimirovich Korchagin and Evgenii Yakovlevich Misochko},
title = {Recent advances in chemistry of high-spin nitrenes},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4965},
number = {1},
pages = {39--69},
doi = {10.1070/RCR4965}
}
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Chapyshev, Sergei Viktorovich, et al. “Recent advances in chemistry of high-spin nitrenes.” Russian Chemical Reviews, vol. 90, no. 1, Nov. 2020, pp. 39-69. https://rcr.colab.ws/publications/10.1070/RCR4965.
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Keywords

azides
EPR spectroscopy
high-spin molecules
molecular magnetism
nitrenes
quantum computation
qubit
qudit
zero-field splitting

Abstract

Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired electrons and having quartet, quintet, sextet or septet ground spin states, published in the last 15 years are analyzed. A comparative analysis of the magnetic properties of high-spin nitrenes and all other known high-spin organic molecules is performed. Promising areas of practical application of high-spin nitrenes as molecular magnets and as qubits and qudits for quantum computations are discussed.

The bibliography includes 214 references.

Funders

Russian Foundation for Basic Research
19-13-50194
Ministry of Education and Science of the Russian Federation
АААА-А19-119070790003-7

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