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Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides

Al'bina Ahmetovna Valeeva 1, 2
Al'bina Ahmetovna Valeeva
, 
Andrey Andreevich Rempel 1, 2, 3
Andrey Andreevich Rempel
, 
Svetlana Vasil'evna Rempel' 1, 2
Svetlana Vasil'evna Rempel'
, 
Stanislav Igorevich Sadovnikov 1
Stanislav Igorevich Sadovnikov
, 
Aleksandr Ivanovich Gusev 1
Aleksandr Ivanovich Gusev
1 Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
2 Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
3 Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Yekaterinburg
10.1070/RCR4967
Published 30 November 2020
Review , RCR4967, Volume 90, Issue 5, 601-626
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Valeeva A. A. et al. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2020. Vol. 90. No. 5. pp. 601-626.
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Valeeva A. A., Rempel A. A., Rempel' S. V., Sadovnikov S. I., Gusev A. I. Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides // Russian Chemical Reviews. 2020. Vol. 90. No. 5. pp. 601-626.
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TY - JOUR
DO - 10.1070/RCR4967
UR - https://rcr.colab.ws/publications/10.1070/RCR4967
TI - Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides
T2 - Russian Chemical Reviews
AU - Valeeva, Al'bina Ahmetovna
AU - Rempel, Andrey Andreevich
AU - Rempel', Svetlana Vasil'evna
AU - Sadovnikov, Stanislav Igorevich
AU - Gusev, Aleksandr Ivanovich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 601-626
IS - 5
VL - 90
ER -
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@article{2020_Valeeva,
author = {Al'bina Ahmetovna Valeeva and Andrey Andreevich Rempel and Svetlana Vasil'evna Rempel' and Stanislav Igorevich Sadovnikov and Aleksandr Ivanovich Gusev},
title = {Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4967},
number = {5},
pages = {601--626},
doi = {10.1070/RCR4967}
}
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Valeeva, Al'bina Ahmetovna, et al. “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides.” Russian Chemical Reviews, vol. 90, no. 5, Nov. 2020, pp. 601-626. https://rcr.colab.ws/publications/10.1070/RCR4967.
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Keywords

carbides
nanocrystalline compounds
nonstoichiometry
oxides
size of nanoparticles
sulfides

Abstract

The results of recent experimental studies of the influence of the size of oxide, carbide and sulfide nanoparticles on changes in their nonstoichiometry are analyzed and generalized. In relation to intrinsically nonstoichiometric titanium oxides and niobium and vanadium carbides, on the one hand, and stoichiometric silver sulfides, on the other hand, it is shown that a decrease in the particle size to the nano scale has a strong impact on the chemical composition of nanocrystalline compounds, viz., it leads to the occurrence of or to increase in nonstoichiometry. A conclusion is drawn that interplay between the particle size and nonstoichiometry is common to all solid nanocrystalline substances and should be taken into account in studies on the synthesis, structure and properties of these systems.

The bibliography includes 260 references.

Funders

Russian Science Foundation
14-23-00025
Ministry of Education and Science of the Russian Federation
0397-2019-0001

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Journal of Experimental and Theoretical Physics , 2019