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C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects

Alexey Alexandrovich Akulov 1, 2
Alexey Alexandrovich Akulov
, 
Mikhail Viktorovich Varaksin 1, 2
Mikhail Viktorovich Varaksin
, 
Valery Nikolaevich Charushin 1, 2
Valery Nikolaevich Charushin
, 
Oleg Nikolaevich Chupakhin 1, 2
Oleg Nikolaevich Chupakhin
1 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ekaterinburg
2 Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
10.1070/RCR4978
Published 30 November 2020
Review , RCR4978, Volume 90, Issue 3, 374-394
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Akulov A. A. et al. C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects // Russian Chemical Reviews. 2020. Vol. 90. No. 3. pp. 374-394.
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Akulov A. A., Varaksin M. V., Charushin V. N., Chupakhin O. N. C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects // Russian Chemical Reviews. 2020. Vol. 90. No. 3. pp. 374-394.
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TY - JOUR
DO - 10.1070/RCR4978
UR - https://rcr.colab.ws/publications/10.1070/RCR4978
TI - C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects
T2 - Russian Chemical Reviews
AU - Akulov, Alexey Alexandrovich
AU - Varaksin, Mikhail Viktorovich
AU - Charushin, Valery Nikolaevich
AU - Chupakhin, Oleg Nikolaevich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 374-394
IS - 3
VL - 90
ER -
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@article{2020_Akulov,
author = {Alexey Alexandrovich Akulov and Mikhail Viktorovich Varaksin and Valery Nikolaevich Charushin and Oleg Nikolaevich Chupakhin},
title = {C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4978},
number = {3},
pages = {374--394},
doi = {10.1070/RCR4978}
}
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Akulov, Alexey Alexandrovich, et al. “C(sp2) -- H functionalization of aldimines and related compounds: advances and prospects.” Russian Chemical Reviews, vol. 90, no. 3, Nov. 2020, pp. 374-394. https://rcr.colab.ws/publications/10.1070/RCR4978.
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Keywords

AZOMETHINES
C–H activation
HYDRAZONES
imines
NITRONES
OXIMES
SCHIFF BASES

Abstract

This is the first systematic review of the most relevant approaches to direct C(sp2) -- H bond functionalization of azomethine derivatives. The scope of the applicability of various transformations is analyzed. The review assesses prospects of the application of this functionalization strategy in the multistep synthesis of valuable compounds for use in medicinal chemistry, materials science and related areas.

The bibliography includes 124 references.

Funders

Russian Foundation for Basic Research
19-13-50193

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