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Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles

Fedor Mikhailovich Dolgushin 1, 2
Fedor Mikhailovich Dolgushin
, 
Igor Leonidovich Eremenko
1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
2 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
Published 30 November 2020
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Dolgushin F. M., Eremenko I. L. Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles // Russian Chemical Reviews. 2020. Vol. 90. No. 12. pp. 1493-1519.
GOST all authors (up to 50)
Dolgushin F. M., Eremenko I. L. Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles // Russian Chemical Reviews. 2020. Vol. 90. No. 12. pp. 1493-1519.
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TY - JOUR
DO - 10.1070/RCR4998
UR - https://rcr.colab.ws/publications/10.1070/RCR4998
TI - Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles
T2 - Russian Chemical Reviews
AU - Dolgushin, Fedor Mikhailovich
AU - Eremenko, Igor Leonidovich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1493-1519
IS - 12
VL - 90
ER -
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@article{2020_Dolgushin,
author = {Fedor Mikhailovich Dolgushin and Igor Leonidovich Eremenko},
title = {Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4998},
number = {12},
pages = {1493--1519},
doi = {10.1070/RCR4998}
}
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Cite this
MLA
Dolgushin, Fedor Mikhailovich, and Igor Leonidovich Eremenko. “Structural chemistry of host--guest molecular architectures based on mercury-containing macrocycles.” Russian Chemical Reviews, vol. 90, no. 12, Nov. 2020, pp. 1493-1519. https://rcr.colab.ws/publications/10.1070/RCR4998.
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Keywords

anion receptors
anticrowns
crystal structure
host-guest complexes
Lewis acid
Lewis base
mercury-containing macrocycles
non-bonded interactions

Abstract

Metallomacrocycles that include several metal ions with the Lewis acid properties are peculiar antipodes of crown ethers (referred to as ``anticrowns'' in the literature). Recently these architectures have been extensively investigated when searching for efficient and selective anion receptors. In this review, we analyze the data on the molecular and crystal structures of supramolecular complexes of mercury-containing macrocycles (hosts) with anions or neutral nucleophiles (guests). The emphasis is on the identification and systematization of the structure types of complexes in dependence of the guest molecule nature, as well as the macrocycle composition and structure. The factors affecting the selectivity of coordination and competitive ability of various electron donor moieties of guest molecules to binding to the macrocycle are considered. The data in the literature on the nonvalent host--guest and host--host interactions, which are responsible for the formation of molecular complexes and their supramolecular association in crystals, are analyzed. The formulated structural regularities of these coordination compounds with an unusual type of molecular architecture open ways to design directly promising molecular materials on their basis.

The bibliography includes 161 references.

Funders

Russian Foundation for Basic Research
19-13-50397
Ministry of Education and Science of the Russian Federation

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