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Modern physical methods for the molecular design of single-molecule magnets

Valentin Vladimirovich Novikov 1
Valentin Vladimirovich Novikov
, 
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RCR5002
Published 30 November 2020
Review , RCR5002, Volume 90, Issue 10, 1330-1358
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Novikov V. V., Nelyubina Y. V. Modern physical methods for the molecular design of single-molecule magnets // Russian Chemical Reviews. 2020. Vol. 90. No. 10. pp. 1330-1358.
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Novikov V. V., Nelyubina Y. V. Modern physical methods for the molecular design of single-molecule magnets // Russian Chemical Reviews. 2020. Vol. 90. No. 10. pp. 1330-1358.
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TY - JOUR
DO - 10.1070/RCR5002
UR - https://rcr.colab.ws/publications/10.1070/RCR5002
TI - Modern physical methods for the molecular design of single-molecule magnets
T2 - Russian Chemical Reviews
AU - Novikov, Valentin Vladimirovich
AU - Nelyubina, Yulia Vladimirovna
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1330-1358
IS - 10
VL - 90
ER -
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@article{2020_Novikov,
author = {Valentin Vladimirovich Novikov and Yulia Vladimirovna Nelyubina},
title = {Modern physical methods for the molecular design of single-molecule magnets},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR5002},
number = {10},
pages = {1330--1358},
doi = {10.1070/RCR5002}
}
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Novikov, Valentin Vladimirovich, and Yulia Vladimirovna Nelyubina. “Modern physical methods for the molecular design of single-molecule magnets.” Russian Chemical Reviews, vol. 90, no. 10, Nov. 2020, pp. 1330-1358. https://rcr.colab.ws/publications/10.1070/RCR5002.
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Keywords

Electron paramagnetic resonance spectroscopy
magnetic anisotropy
magnetometry
molecular design
molecular magnetism
nuclear magnetic resonance spectroscopy
optical spectroscopy
single-molecule magnets
X-ray diffraction

Abstract

Many paramagnetic metal complexes have emerged as unique magnetic materials (single-molecule magnets), which behave as conventional magnets at the single-molecule level, thereby making it possible to use them in modern devices for data storage and processing. The rational design of these complexes, however, requires a deep understanding of the physical laws behind a single-molecule magnet behaviour, the mechanisms of magnetic relaxation that determines the magnetic properties and the relationship of these properties with the structure of single-molecule magnets. This review focuses on the physical methods providing such understanding, including different versions and various combinations of magnetometry, electron paramagnetic and nuclear magnetic resonance spectroscopy, optical spectroscopy and X-ray diffraction. Many of these methods are traditionally used to determine the composition and structure of new chemical compounds. However, they are rarely applied to study molecular magnetism.

The bibliography includes 224 references.

Funders

Russian Foundation for Basic Research
19-13-50487

References

1.
rcr_90_10_1330_bib1
Kahn
1993
3.
Magnetic bistability in a metal-ion cluster
Sessoli R., Gatteschi D., Caneschi A., Novak M.A.
Nature , 1993
4.
Single-Molecule Magnets
Christou G., Gatteschi D., Hendrickson D.N., Sessoli R.
MRS Bulletin , 2000
5.
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Ferrando-Soria J., Vallejo J., Castellano M., Martínez-Lillo J., Pardo E., Cano J., Castro I., Lloret F., Ruiz-García R., Julve M.
Coordination Chemistry Reviews , 2017
6.
Emerging trends in spin crossover (SCO) based functional materials and devices
Senthil Kumar K., Ruben M.
Coordination Chemistry Reviews , 2017
7.
Dicopper(II) pyrazolenophanes: Ligand effects on their structures and magnetic properties
Castro I., Barros W.P., Calatayud M.L., Lloret F., Marino N., De Munno G., Stumpf H.O., Ruiz-García R., Julve M.
Coordination Chemistry Reviews , 2016
9.
Single chain magnets: where to from here?
Bogani L., Vindigni A., Sessoli R., Gatteschi D.
Journal of Materials Chemistry A , 2008
10.
Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
López-Cabrelles J., Mañas-Valero S., Vitórica-Yrezábal I.J., Bereciartua P.J., Rodríguez-Velamazán J.A., Waerenborgh J.C., Vieira B.J., Davidovikj D., Steeneken P.G., van der Zant H.S., Mínguez Espallargas G., Coronado E.
Nature Chemistry , 2018
11.
Dynamic magnetic MOFs
Coronado E., Mínguez Espallargas G.
Chemical Society Reviews , 2013
12.
All-inorganic single ion magnets in ceramic matrices.
Zykin M.A., Kazin P.E., Jansen M.
Chemistry - A European Journal , 2020
13.
Molecular/Polymeric Magnets
Epstein A.J., Miller J.S.
Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals , 1993
14.
Magnetic Information Storage on Polymers by Using Patterned Single-Molecule Magnets
Cavallini M., Gomez-Segura J., Ruiz-Molina D., Massi M., Albonetti C., Rovira C., Veciana J., Biscarini F.
Angewandte Chemie - International Edition , 2005
16.
Molecular spintronics using single-molecule magnets
Bogani L., Wernsdorfer W.
Nature Materials , 2008
17.
Organometallic Single-Molecule Magnets
Layfield R.A.
Organometallics , 2014
19.
Uncommon lanthanide ions in purely 4f Single Molecule Magnets
Pointillart F., Cador O., Le Guennic B., Ouahab L.
Coordination Chemistry Reviews , 2017
22.
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Guo F., Day B.M., Chen Y., Tong M., Mansikkamäki A., Layfield R.A.
Science , 2018
23.
Inelastic Neutron Scattering and Magnetic Susceptibilities of the Single-Molecule Magnets [Mn4O3X(OAc)3(dbm)3] (X = Br, Cl, OAc, and F):  Variation of the Anisotropy along the Series
Andres H., Basler R., Güdel H., Aromí G., Christou G., Büttner H., Rufflé B.
Journal of the American Chemical Society , 2000
24.
rcr_90_10_1330_bib24
Sessoli
2010
25.
Local magnetic susceptibility of the muon in the molecular nano-magnet
Salman Z., Kiefl R.F., Chow K.H., MacFarlane W.A., Keeler T.A., Parolin T.J., Wang D.
Physica B: Condensed Matter , 2009
27.
A Record Anisotropy Barrier for a Single-Molecule Magnet
Milios C.J., Vinslava A., Wernsdorfer W., Moggach S., Parsons S., Perlepes S.P., Christou G., Brechin E.K.
Journal of the American Chemical Society , 2007
28.
Polymer-metal hybrid transparent electrodes for flexible electronics
Kang H., Jung S., Jeong S., Kim G., Lee K.
Nature Communications , 2015
29.
A ferromagnetically coupled mn(19) aggregate with a record S=83/2 ground spin state.
Ako A.M., Hewitt I.J., Mereacre V., Clérac R., Wernsdorfer W., Anson C.E., Powell A.K.
Angewandte Chemie - International Edition , 2006
30.
What is not required to make a single molecule magnet
Neese F., Pantazis D.A.
Faraday Discussions , 2011
32.
A linear cobalt(II) complex with maximal orbital angular momentum from a non-Aufbau ground state
Bunting P.C., Atanasov M., Damgaard-Møller E., Perfetti M., Crassee I., Orlita M., Overgaard J., van Slageren J., Neese F., Long J.R.
Science , 2018
33.
Basics of the spin Hamiltonian formalism
Mostafanejad M.
International Journal of Quantum Chemistry , 2014
34.
rcr_90_10_1330_bib35
Abragam
1970
35.
rcr_90_10_1330_bib36
Waller
Z. Phys. Hadrons Nuclei , 1932
36.
rcr_90_10_1330_bib37
Abragam
2012
37.
Improving f-element single molecule magnets
Liddle S.T., van Slageren J.
Chemical Society Reviews , 2015
38.
Time effects in the magnetic cooling method─I
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences , 1936
40.
rcr_90_10_1330_bib41
Kramers
Proc. Acad. Amsterdam Acad. , 1930
41.
Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets
Chen Y., Liu J., Ungur L., Liu J., Li Q., Wang L., Ni Z., Chibotaru L.F., Chen X., Tong M.
Journal of the American Chemical Society , 2016
42.
A monometallic lanthanide bis(methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour
Gregson M., Chilton N.F., Ariciu A., Tuna F., Crowe I.F., Lewis W., Blake A.J., Collison D., McInnes E.J., Winpenny R.E., Liddle S.T.
Chemical Science , 2016
43.
Mesoscopic quantum tunneling of the magnetization
Barbara B., Wernsdorfer W., Sampaio L.C., Park J.G., Paulsen C., Novak M.A., Ferré R., Mailly D., Sessoli R., Caneschi A., Hasselbach K., Benoit A., Thomas L.
Journal of Magnetism and Magnetic Materials , 1995
44.
rcr_90_10_1330_bib45
Paulsen
1995
45.
Macroscopic measurement of resonant magnetization tunneling in high-spin molecules.
Friedman J.R., Sarachik M.P., Tejada J., Ziolo R.
Physical Review Letters , 1996
46.
Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets
Thomas L., Lionti F., Ballou R., Gatteschi D., Sessoli R., Barbara B.
Nature , 1996
52.
Consequences of a linear two-coordinate geometry for the orbital magnetism and Jahn-Teller distortion behavior of the high spin iron(II) complex Fe[N(t-Bu)2]2.
Reiff W.M., Schulz C.E., Whangbo M., Seo J.I., Lee Y.S., Potratz G.R., Spicer C.W., Girolami G.S.
Journal of the American Chemical Society , 2008
53.
Slow magnetization dynamics in a series of two-coordinate iron(ii) complexes
Zadrozny J.M., Atanasov M., Bryan A.M., Lin C., Rekken B.D., Power P.P., Neese F., Long J.R.
Chemical Science , 2013
54.
Magnetic blocking in a linear iron(I) complex.
Zadrozny J.M., Xiao D.J., Atanasov M., Long G.J., Grandjean F., Neese F., Long J.R.
Nature Chemistry , 2013
55.
Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences , 1937
58.
Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets
Wernsdorfer W., Aliaga-Alcalde N., Hendrickson D.N., Christou G.
Nature , 2002
60.
Photosynthetic water oxidation center: spin frustration in distorted cubane MnIVMnIII3 model complexes
Hendrickson D.N., Christou G., Schmitt E.A., Libby E., Bashkin J.S., Wang S., Tsai H.L., Vincent J.B., Boyd P.D.
Journal of the American Chemical Society , 1992
64.
Effects of Nuclear Spins on the Quantum Relaxation of the Magnetization for the Molecular NanomagnetFe8
Wernsdorfer W., Caneschi A., Sessoli R., Gatteschi D., Cornia A., Villar V., Paulsen C.
Physical Review Letters , 2000
65.
Spin-Spin Cross Relaxation in Single-Molecule Magnets
Wernsdorfer W., Bhaduri S., Tiron R., Hendrickson D.N., Christou G.
Physical Review Letters , 2002
66.
Slow Magnetic Relaxation in a CoII-YIIISingle-Ion Magnet with Positive Axial Zero-Field Splitting
Colacio E., Ruiz J., Ruiz E., Cremades E., Krzystek J., Carretta S., Cano J., Guidi T., Wernsdorfer W., Brechin E.K.
Angewandte Chemie - International Edition , 2013
68.
A Room-Temperature Molecular/Organic-Based Magnet
Manriquez J.M., Yee G.T., McLean R.S., Epstein A.J., Miller J.S.
Science , 1991
69.
Organic- and molecule-based magnets
Miller J.S.
Materials Today , 2014
70.
Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level
Ishikawa N., Sugita M., Ishikawa T., Koshihara S., Kaizu Y.
Journal of the American Chemical Society , 2003
71.
Giant field dependence of the low temperature relaxation of the magnetization in a dysprosium(III)-DOTA complex.
Car P., Perfetti M., Mannini M., Favre A., Caneschi A., Sessoli R.
Chemical Communications , 2011
72.
A Mononuclear Dysprosium Complex Featuring Single‐Molecule‐Magnet Behavior
Jiang S., Wang B., Su G., Wang Z., Gao S.
Angewandte Chemie , 2010
74.
Theory of Spin–Lattice Relaxation
Shrivastava K.N.
Physica Status Solidi (B): Basic Research , 1983
75.
rcr_90_10_1330_bib76
Abragam
1961
76.
MIXED QUANTUM-THERMAL RELAXATION IN MN12 ACETATE MOLECULES
Fort A., Rettori A., Villain J., Gatteschi D., Sessoli R.
Physical Review Letters , 1998
77.
Spin-Lattice Relaxation in Multilevel Spin Systems
Orbach R., Blume M.
Physical Review Letters , 1962
78.
Optical‐acoustic two‐phonon relaxation in spin systems
Singh A., Shrivastava K.N.
Physica Status Solidi (B): Basic Research , 1979
79.
rcr_90_10_1330_bib80
Feng
Chem. Commun. , 2016
80.
Mössbauer spectroscopy as a probe of magnetization dynamics in the linear iron(I) and iron(II) complexes [Fe(C(SiMe3)3)2](1-/0.).
Zadrozny J.M., Xiao D.J., Long J.R., Atanasov M., Neese F., Grandjean F., Long G.J.
Inorganic Chemistry , 2013
81.
Magnetization Density in an Iron(III) Magnetic Cluster. A Polarized Neutron Investigation
Pontillon Y., Caneschi A., Gatteschi D., Sessoli R., Ressouche E., Schweizer J., Lelievre-Berna E.
Journal of the American Chemical Society , 1999
82.
X‐Ray Magnetic Circular Dichroism Picks out Single‐Molecule Magnets Suitable for Nanodevices
Mannini M., Pineider F., Sainctavit P., Joly L., Fraile-Rodríguez A., Arrio M., Cartier dit Moulin C., Wernsdorfer W., Cornia A., Gatteschi D., Sessoli R.
Advanced Materials , 2009
83.
X-ray magnetic circular dichroism—A versatile tool to study magnetism
van der Laan G., Figueroa A.I.
Coordination Chemistry Reviews , 2014
84.
X‐Ray Detected Magnetic Hysteresis of Thermally Evaporated Terbium Double‐Decker Oriented Films
Margheriti L., Chiappe D., Mannini M., Car P., Sainctavit P., Arrio M., de Mongeot F.B., Cezar J.C., Piras F.M., Magnani A., Otero E., Caneschi A., Sessoli R.
Advanced Materials , 2010
85.
rcr_90_10_1330_bib86
Lancaster
J. Phys.: Condens. Matter , 2004
86.
as a probe of anisotropy in low-dimensional molecular magnets
Blundell S.J., Lancaster T., Pratt F.L., Baker P.J., Brooks M.L., Baines C., Manson J.L., Landee C.P.
Journal of Physics and Chemistry of Solids , 2007
88.
Microscopic spin Hamiltonian of aCr8antiferromagnetic ring from inelastic neutron scattering
Carretta S., van Slageren J., Guidi T., Liviotti E., Mondelli C., Rovai D., Cornia A., Dearden A.L., Carsughi F., Affronte M., Frost C.D., Winpenny R.E., Gatteschi D., Amoretti G., Caciuffo R., et. al.
Physical Review B , 2003
89.
Magnetic relaxation studies on a single-molecule magnet by time-resolved inelastic neutron scattering
Waldmann O., Carver G., Dobe C., Biner D., Sieber A., Güdel H.U., Mutka H., Ollivier J., Chakov N.E.
Applied Physics Letters , 2006
90.
rcr_90_10_1330_bib91
Baker
2014
91.
rcr_90_10_1330_bib92
McInnes
2006
92.
Versatile and Sensitive Vibrating‐Sample Magnetometer
Foner S.
Review of Scientific Instruments , 1959
93.
rcr_90_10_1330_bib94
Carlin
1986
95.
rcr_90_10_1330_bib96
Gatteschi
2006
96.
Angular‐Resolved Magnetometry Beyond Triclinic Crystals: Out‐of‐Equilibrium Studies of Cp*ErCOT Single‐Molecule Magnet
Boulon M., Cucinotta G., Liu S., Jiang S., Ungur L., Chibotaru L.F., Gao S., Sessoli R.
Chemistry - A European Journal , 2013
97.
Understanding magnetic relaxation in single-ion magnets with high blocking temperature
Chiesa A., Cugini F., Hussain R., Macaluso E., Allodi G., Garlatti E., Giansiracusa M., Goodwin C.A., Ortu F., Reta D., Skelton J.M., Guidi T., Santini P., Solzi M., De Renzi R., et. al.
Physical Review B , 2020
98.
Alternating current susceptibility, high field magnetization, and millimeter band EPR evidence for a ground S = 10 state in [Mn12O12(Ch3COO)16(H2O)4].2CH3COOH.4H2O
Caneschi A., Gatteschi D., Sessoli R., Barra A.L., Brunel L.C., Guillot M.
Journal of the American Chemical Society , 1991
99.
rcr_90_10_1330_bib100
Argand
1874
100.
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole K.S., Cole R.H.
Journal of Chemical Physics , 1941
102.
rcr_90_10_1330_bib103
Nemec
Dalton Trans. , 2015
103.
Magnetic Anisotropy and Field‐induced Slow  Relaxation of Magnetization in Tetracoordinate CoII Compound [Co(CH3‐im)2Cl2]
Nemec I., Herchel R., Kern M., Neugebauer P., van Slageren J., Trávníček Z.
Materials , 2017
104.
Tuning Magnetic Anisotropy Through Ligand Substitution in Five-Coordinate Co(II) Complexes
Schweinfurth D., Krzystek J., Atanasov M., Klein J., Hohloch S., Telser J., Demeshko S., Meyer F., Neese F., Sarkar B.
Inorganic Chemistry , 2017
105.
Transition Ion Strikes Back: Large Magnetic Susceptibility Anisotropy in Cobalt(II) Clathrochelates
Novikov V.V., Pavlov A.A., Belov A.S., Vologzhanina A.V., Savitsky A., Voloshin Y.Z.
Journal of Physical Chemistry Letters , 2014
108.
High-Frequency EPR Spectroscopy of Large Metal Ion Clusters: From Zero Field Splitting to Quantum Tunneling of the Magnetization
Barra A., Brunel L., Gatteschi D., Pardi L., Sessoli R.
Accounts of Chemical Research , 1998
109.
Terahertz BWO-spectrosopy
Gorshunov B., Volkov A., Spektor I., Prokhorov A., Mukhin A., Dressel M., Uchida S., Loidl A.
International Journal of Infrared and Millimeter Waves , 2005
110.
A THz spectrometer combining the free electron laser FLARE with 33 T magnetic fields
Ozerov M., Bernáth B., Kamenskyi D., Redlich B., van der Meer A.F., Christianen P.C., Engelkamp H., Maan J.C.
Applied Physics Letters , 2017
111.
Terahertz-range free-electron laser electron spin resonance spectroscopy: techniques and applications in high magnetic fields.
Zvyagin S.A., Ozerov M., Čižmár E., Kamenskyi D., Zherlitsyn S., Herrmannsdörfer T., Wosnitza J., Wünsch R., Seidel W.
Review of Scientific Instruments , 2009
112.
X-band EPR setup with THz light excitation of Novosibirsk Free Electron Laser: Goals, means, useful extras
Veber S.L., Tumanov S.V., Fursova E.Y., Shevchenko O.A., Getmanov Y.V., Scheglov M.A., Kubarev V.V., Shevchenko D.A., Gorbachev I.I., Salikova T.V., Kulipanov G.N., Ovcharenko V.I., Fedin M.V.
Journal of Magnetic Resonance , 2018
115.
Bridging the terahertz gap
Won R.
Nature Photonics , 2010
116.
Frequency-domain magnetic resonance spectroscopy of molecular magnetic materials
van Slageren J., Vongtragool S., Gorshunov B., Mukhin A.A., Karl N., Krzystek J., Telser J., Müller A., Sangregorio C., Gatteschi D., Dressel M.
Physical Chemistry Chemical Physics , 2003
117.
A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier
Rechkemmer Y., Breitgoff F.D., van der Meer M., Atanasov M., Hakl M., Orlita M., Neugebauer P., Neese F., Sarkar B., van Slageren J.
Nature Communications , 2016
118.
Comprehensive Spectroscopic Determination of the Crystal Field Splitting in an Erbium Single-Ion Magnet
Rechkemmer Y., Fischer J.E., Marx R., Dörfel M., Neugebauer P., Horvath S., Gysler M., Brock-Nannestad T., Frey W., Reid M.F., van Slageren J.
Journal of the American Chemical Society , 2015
119.
Accurate and unequivocal determination of the crystal-field parameters of lanthanide ions via a multitechnique approach
Slota M., Jiang S., Heintze E., Rechkemmer Y., Dressel M., van Slageren J., Bogani L.
Physical Review B , 2019
120.
A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling.
Pavlov A.A., Aleshin D.Y., Savkina S.A., Belov A.S., Efimov N.N., Nehrkorn J., Ozerov M., Voloshin Y.Z., Nelyubina Y.V., Novikov V.V.
ChemPhysChem , 2019
121.
Detailed electronic structure of a high-spin cobalt(ii) complex determined from NMR and THz-EPR spectroscopy.
Pavlov A.A., Nehrkorn J., Pankratova Y.A., Ozerov M., Mikhalyova E.A., Polezhaev A.V., Nelyubina Y.V., Novikov V.V.
Physical Chemistry Chemical Physics , 2019
122.
Spin–phonon couplings in transition metal complexes with slow magnetic relaxation
Moseley D.H., Stavretis S.E., Thirunavukkuarasu K., Ozerov M., Cheng Y., Daemen L.L., Ludwig J., Lu Z., Smirnov D., Brown C.M., Pandey A., Ramirez-Cuesta A.J., Lamb A.C., Atanasov M., Bill E., et. al.
Nature Communications , 2018
123.
A Synergy and Struggle of EPR, Magnetometry and NMR: A Case Study of Magnetic Interaction Parameters in a Six-Coordinate Cobalt(II) Complex
Pavlov A.A., Nehrkorn J., Zubkevich S.V., Fedin M.V., Holldack K., Schnegg A., Novikov V.V.
Inorganic Chemistry , 2020
124.
Purely Spectroscopic Determination of the Spin Hamiltonian Parameters in High-Spin Six-Coordinated Cobalt(II) Complexes with Large Zero-Field Splitting
Misochko E.Y., Akimov A.V., Korchagin D.V., Nehrkorn J., Ozerov M., Palii A.V., Clemente-Juan J.M., Aldoshin S.M.
Inorganic Chemistry , 2019
125.
Recent progress in synchrotron-based frequency-domain Fourier-transform THz-EPR
Nehrkorn J., Holldack K., Bittl R., Schnegg A.
Journal of Magnetic Resonance , 2017
126.
Frequency‐Domain Fourier‐Transform Terahertz Spectroscopy of the Single‐Molecule Magnet (NEt4)[Mn2(5‐Brsalen)2(MeOH)2Cr(CN)6]
Dreiser J., Schnegg A., Holldack K., Pedersen K.S., Schau-Magnussen M., Nehrkorn J., Tregenna-Piggott P., Mutka H., Weihe H., Bendix J., Waldmann O.
Chemistry - A European Journal , 2011
127.
Determination of Large Zero-Field Splitting in High-Spin Co(I) Clathrochelates
Nehrkorn J., Veber S.L., Zhukas L.A., Novikov V.V., Nelyubina Y.V., Voloshin Y.Z., Holldack K., Stoll S., Schnegg A.
Inorganic Chemistry , 2018
128.
Design of Single-Molecule Magnets: Insufficiency of the Anisotropy Barrier as the Sole Criterion
Pedersen K.S., Dreiser J., Weihe H., Sibille R., Johannesen H.V., Sørensen M.A., Nielsen B.E., Sigrist M., Mutka H., Rols S., Bendix J., Piligkos S.
Inorganic Chemistry , 2015
129.
A High-Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single-Ion-Magnet Behavior and Lanthanide Luminescence
Long J., Rouquette J., Thibaud J., Ferreira R.A., Carlos L.D., Donnadieu B., Vieru V., Chibotaru L.F., Konczewicz L., Haines J., Guari Y., Larionova J.
Angewandte Chemie - International Edition , 2014
130.
Characterization of electronic transitions in complex molecules
Kasha M.
Discussions of the Faraday Society , 1950
131.
Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization
Perfetti M., Gysler M., Rechkemmer-Patalen Y., Zhang P., Taştan H., Fischer F., Netz J., Frey W., Zimmermann L.W., Schleid T., Hakl M., Orlita M., Ungur L., Chibotaru L., Brock-Nannestad T., et. al.
Chemical Science , 2019
132.
A bifunctional luminescent single-ion magnet: towards correlation between luminescence studies and magnetic slow relaxation processes
Long J., Vallat R., Ferreira R.A., Carlos L.D., Almeida Paz F.A., Guari Y., Larionova J.
Chemical Communications , 2012
133.
rcr_90_10_1330_bib134
Long
RSC Adv. , 2016
134.
Thermostability and photoluminescence of Dy(iii) single-molecule magnets under a magnetic field
Bi Y., Chen C., Zhao Y., Zhang Y., Jiang S., Wang B., Han J., Sun J., Bian Z., Wang Z., Gao S.
Chemical Science , 2016
135.
Energy Levels ofYb3+in Gallium and Aluminum Garnets. I. Spectra
Buchanan R.A., Wickersheim K.A., Pearson J.J., Herrmann G.F.
Physical Review A , 1967
136.
Recent advances in luminescent lanthanide based Single-Molecule Magnets
Long J., Guari Y., Ferreira R.A., Carlos L.D., Larionova J.
Coordination Chemistry Reviews , 2018
137.
Some Rules of Spectral Structure*
Laporte O., Meggers W.F.
Journal of the Optical Society of America , 1925
138.
A delocalized arene-bridged diuranium single-molecule magnet
Mills D.P., Moro F., McMaster J., van Slageren J., Lewis W., Blake A.J., Liddle S.T.
Nature Chemistry , 2011
139.
rcr_90_10_1330_bib140
Mason
2006
140.
rcr_90_10_1330_bib141
Mason
2006
141.
Magneto-Structural Correlations in Pseudotetrahedral Forms of the [Co(SPh)4]2– Complex Probed by Magnetometry, MCD Spectroscopy, Advanced EPR Techniques, and ab Initio Electronic Structure Calculations
Suturina E.A., Nehrkorn J., Zadrozny J.M., Liu J., Atanasov M., Weyhermüller T., Maganas D., Hill S., Schnegg A., Bill E., Long J.R., Neese F.
Inorganic Chemistry , 2017
142.
Magnetism of isolated Mn 12 single-molecule magnets detected by magnetic circular dichroism: Observation of spin tunneling with a magneto-optical technique
Domingo N., Williamson B.E., Gómez-Segura J., Gerbier P., Ruiz-Molina D., Amabilino D.B., Veciana J., Tejada J.
Physical Review B , 2004
144.
Pseudocontact shifts in biomolecular NMR using paramagnetic metal tags.
Nitsche C., Otting G.
Progress in Nuclear Magnetic Resonance Spectroscopy , 2017
147.
Perspectives on paramagnetic NMR from a life sciences infrastructure
Ravera E., Parigi G., Luchinat C.
Journal of Magnetic Resonance , 2017
148.
Employing paramagnetic shift for responsive MRI probes
Harnden A.C., Parker D., Rogers N.J.
Coordination Chemistry Reviews , 2019
149.
A new paramagnetically shifted imaging probe for MRI
Senanayake P.K., Rogers N.J., Finney K.N., Harvey P., Funk A.M., Wilson J.I., O'Hogain D., Maxwell R., Parker D., Blamire A.M.
Magnetic Resonance in Medicine , 2016
150.
Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry
Blackburn O.A., Edkins R.M., Faulkner S., Kenwright A.M., Parker D., Rogers N.J., Shuvaev S.
Dalton Transactions , 2016
151.
Pseudocontact shifts and paramagnetic susceptibility in semiempirical and quantum chemistry theories
Parigi G., Benda L., Ravera E., Romanelli M., Luchinat C.
Journal of Chemical Physics , 2019
152.
Pseudo‐Contact NMR Shifts over the Paramagnetic Metalloprotein CoMMP‐12 from First Principles
Benda L., Mareš J., Ravera E., Parigi G., Luchinat C., Kaupp M., Vaara J.
Angewandte Chemie - International Edition , 2016
155.
rcr_90_10_1330_bib156
Pavlov
Inorg. Chem. , 2017
157.
Diamagnetic Corrections and Pascal's Constants
Bain G.A., Berry J.F.
Journal of Chemical Education , 2008
158.
Paramagnetic NMR in solution and the solid state.
Pell A.J., Pintacuda G., Grey C.P.
Progress in Nuclear Magnetic Resonance Spectroscopy , 2019
159.
Recent advances in biological applications of cage metal complexes
Voloshin Y.Z., Novikov V.V., Nelyubina Y.V.
RSC Advances , 2015
160.
rcr_90_10_1330_bib161
Van Vleck
1932
162.
Paramagnetic NMR Analysis of Substituted Biscyclooctatetraene Lanthanide Complexes
Hiller M., Maier M., Wadepohl H., Enders M.
Organometallics , 2016
163.
Sandwich-type tetrakis(phthalocyaninato) dysprosium–cadmium quadruple-decker SMM
Wang H., Qian K., Wang K., Bian Y., Jiang J., Gao S.
Chemical Communications , 2011
165.
Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures
Wang H., Wang B., Bian Y., Gao S., Jiang J.
Coordination Chemistry Reviews , 2016
166.
Determination of ligand field splitting in lanthanide(iii) monoporphyrinato complexes
Santria A., Fuyuhiro A., Fukuda T., Ishikawa N.
Dalton Transactions , 2019
168.
rcr_90_10_1330_bib169
Hiller
Chem. – Eur. J. , 2019
169.
A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior
Novikov V.V., Pavlov A.A., Nelyubina Y.V., Boulon M., Varzatskii O.A., Voloshin Y.Z., Winpenny R.E.
Journal of the American Chemical Society , 2015
170.
Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy
Pavlov A.A., Savkina S.A., Belov A.S., Nelyubina Y.V., Efimov N.N., Voloshin Y.Z., Novikov V.V.
Inorganic Chemistry , 2017
171.
A New Single-Molecule Magnet Based on a Cage Cobalt(II) Complex
Aleshin D.Y., Pavlov A.A., Belova S.A., Efimov N.N., Belov A.S., Novikov V.V., Voloshin Y.Z.
Russian Journal of Inorganic Chemistry , 2019
174.
Pseudocontact shifts from mobile spin labels
Suturina E.A., Kuprov I.
Physical Chemistry Chemical Physics , 2016
175.
Polymorphism in a Cobalt-Based Single-Ion Magnet Tuning Its Barrier to Magnetization Relaxation
Pavlov A.A., Nelyubina Y.V., Kats S.V., Penkova L.V., Efimov N.N., Dmitrienko A.O., Vologzhanina A.V., Belov A.S., Voloshin Y.Z., Novikov V.V.
Journal of Physical Chemistry Letters , 2016
176.
In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes
Pankratova Y., Aleshin D., Nikovskiy I., Novikov V., Nelyubina Y.
Inorganic Chemistry , 2020
177.
Magnetic Memory in an Isotopically Enriched and Magnetically Isolated Mononuclear Dysprosium Complex
Pointillart F., Bernot K., Golhen S., Le Guennic B., Guizouarn T., Ouahab L., Cador O.
Angewandte Chemie , 2014
178.
Polarized neutron diffraction and its application to spin density studies
Dougan B.A., Xue Z.
Science in China Series B Chemistry , 2009
179.
Mapping the Magnetic Anisotropy at the Atomic Scale in Dysprosium Single‐Molecule Magnets
Klahn E.A., Gao C., Gillon B., Gukasov A., Fabrèges X., Piltz R.O., Jiang S., Overgaard J.
Chemistry - A European Journal , 2018
180.
Polarized Neutron Diffraction to Probe Local Magnetic Anisotropy of a Low‐Spin Fe(III) Complex
Ridier K., Mondal A., Boilleau C., Cador O., Gillon B., Chaboussant G., Le Guennic B., Costuas K., Lescouëzec R.
Angewandte Chemie - International Edition , 2016
181.
First experimental charge density study using a Bruker CMOS-type PHOTON 100 detector: the case of ammonium tetraoxalate dihydrate
Jarzembska K.N., Kamiński R., Dobrzycki Ł., Cyrański M.K.
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials , 2014
182.
Zerstreuung von Röntgenstrahlen
Debye P.
Annalen der Physik , 1915
183.
Inhomogeneous Electron Gas
Hohenberg P., Kohn W.
Physical Review A , 1964
184.
rcr_90_10_1330_bib186
Meng
Angew. Chem., Int. Ed. , 2020
185.
Influence of anion induced geometry change in Zn(ii) on the magnetization relaxation dynamics of Dy(iii) in Zn–Dy–Zn complexes
Shukla P., Ansari K.U., Gao C., Vaidya S., Tripathi S., Kumar P., Butcher R.J., Overgaard J., Shanmugam M.
Dalton Transactions , 2020
186.
Two-Coordinate Co(II) Imido Complexes as Outstanding Single-Molecule Magnets
Yao X., Du J., Zhang Y., Leng X., Yang M., Jiang S., Wang Z., Ouyang Z., Deng L., Wang B., Gao S.
Journal of the American Chemical Society , 2016
188.
Mononuclear Single-Molecule Magnets: Tailoring the Magnetic Anisotropy of First-Row Transition-Metal Complexes
Gomez-Coca S., Cremades E., Aliaga-Alcalde N., Ruiz E.
Journal of the American Chemical Society , 2013
190.
A capped trigonal prismatic cobalt(ii) complex as a structural archetype for single-ion magnets
Yi G., Cui H., Zhang C., Zhao W., Chen L., Zhang Y., Chen X., Song Y., Yuan A.
Dalton Transactions , 2020
191.
Coordination [CoII2] and [CoIIZnII] Helicates Showing Slow Magnetic Relaxation
Diego R., Pavlov A., Darawsheh M., Aleshin D., Nehrkorn J., Nelyubina Y., Roubeau O., Novikov V., Aromí G.
Inorganic Chemistry , 2019
192.
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness
Nishita M., Park S., Nishio T., Kamizaki K., Wang Z., Tamada K., Takumi T., Hashimoto R., Otani H., Pazour G.J., Hsu V.W., Minami Y.
Scientific Reports , 2017
194.
Investigating Magnetostructural Correlations in the Pseudooctahedral trans-[NiII{(OPPh2)(EPPh2)N}2(sol)2] Complexes (E = S, Se; sol = DMF, THF) by Magnetometry, HFEPR, and ab Initio Quantum Chemistry
Maganas D., Krzystek J., Ferentinos E., Whyte A.M., Robertson N., Psycharis V., Terzis A., Neese F., Kyritsis P.
Inorganic Chemistry , 2012
195.
Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?
Qian K., Baldoví J.J., Jiang S., Gaita-Ariño A., Zhang Y., Overgaard J., Wang B., Coronado E., Gao S.
Chemical Science , 2015
196.
High-Pressure Crystallographic and Magnetic Studies of Pseudo-D5h Symmetric Dy(III) and Ho(III) Single-Molecule Magnets
Norre M.S., Gao C., Dey S., Gupta S.K., Borah A., Murugavel R., Rajaraman G., Overgaard J.
Inorganic Chemistry , 2019
197.
High-Pressure Crystallography as a Guide in the Design of Single-Molecule Magnets
Thiel A.M., Damgaard-Møller E., Overgaard J.
Inorganic Chemistry , 2020
199.
First-principles calculations of zero-field splitting parameters
Ganyushin D., Neese F.
Journal of Chemical Physics , 2006
201.
Quantum chemical methods in charge density studies from X-ray diffraction data
Korlyukov A.A., Nelyubina Y.V.
Russian Chemical Reviews , 2019
202.
rcr_90_10_1330_bib205
Aslanov
1989
203.
Testing aspherical atom refinements on small-molecule data sets
Hansen N.K., Coppens P.
Acta Crystallographica Section A , 1978
204.
Charge Densities Come of Age
Coppens P.
Angewandte Chemie - International Edition , 2005
205.
rcr_90_10_1330_bib208
Gatti
2012
206.
Determination of d-Orbital Populations in a Cobalt(II) Single-Molecule Magnet Using Single-Crystal X-ray Diffraction
Craven M., Nygaard M.H., Zadrozny J.M., Long J.R., Overgaard J.
Inorganic Chemistry , 2018
207.
rcr_90_10_1330_bib210
Damgaard-Mùller
2020
210.
rcr_90_10_1330_bib213
Bader
1994
211.
rcr_90_10_1330_bib214
Damgaard-Mùller
Angew. Chem., Int. Ed. , 2020
213.
Insights into Single-Molecule-Magnet Behavior from the Experimental Electron Density of Linear Two-Coordinate Iron Complexes
Thomsen M.K., Nyvang A., Walsh J.P., Bunting P.C., Long J.R., Neese F., Atanasov M., Genoni A., Overgaard J.
Inorganic Chemistry , 2019
215.
On Building a Data Bank of Transferable Experimental Electron Density Parameters Applicable to Polypeptides
Pichon-Pesme V., Lecomte C., Lachekar H.
The Journal of Physical Chemistry , 1995
216.
Room-Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits
Atzori M., Tesi L., Morra E., Chiesa M., Sorace L., Sessoli R.
Journal of the American Chemical Society , 2016
217.
Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy
Gómez-Coca S., Urtizberea A., Cremades E., Alonso P.J., Camón A., Ruiz E., Luis F.
Nature Communications , 2014
218.
Boron-Pyrazole Chemistry
Trofimenko S.
Journal of the American Chemical Society , 1966
219.
Electron Spin Resonance of Vanadyl Phthalocyanine
Assour J.M., Goldmacher J., Harrison S.E.
Journal of Chemical Physics , 1965
220.
Boron-pyrazole chemistry. II. Poly(1-pyrazolyl)-borates
Trofimenko S.
Journal of the American Chemical Society , 1967