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New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents

Igor Vladimirovich Pletnev 1
Igor Vladimirovich Pletnev
, 
Svetlana Valerievna Smirnova 1
Svetlana Valerievna Smirnova
, 
Andrei Victorovich Sharov 1
Andrei Victorovich Sharov
, 
Yurii Aleksandrovich Zolotov 1
Yurii Aleksandrovich Zolotov
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RCR5007
Published 30 November 2020
Review , RCR5007, Volume 90, Issue 9, 1109-1141
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Pletnev I. V. et al. New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents // Russian Chemical Reviews. 2020. Vol. 90. No. 9. pp. 1109-1141.
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Pletnev I. V., Smirnova S. V., Sharov A. V., Zolotov Y. A. New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents // Russian Chemical Reviews. 2020. Vol. 90. No. 9. pp. 1109-1141.
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TY - JOUR
DO - 10.1070/RCR5007
UR - https://rcr.colab.ws/publications/10.1070/RCR5007
TI - New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents
T2 - Russian Chemical Reviews
AU - Pletnev, Igor Vladimirovich
AU - Smirnova, Svetlana Valerievna
AU - Sharov, Andrei Victorovich
AU - Zolotov, Yurii Aleksandrovich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1109-1141
IS - 9
VL - 90
ER -
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@article{2020_Pletnev,
author = {Igor Vladimirovich Pletnev and Svetlana Valerievna Smirnova and Andrei Victorovich Sharov and Yurii Aleksandrovich Zolotov},
title = {New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR5007},
number = {9},
pages = {1109--1141},
doi = {10.1070/RCR5007}
}
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Pletnev, Igor Vladimirovich, et al. “New generation extraction solvents: from ionic liquids and aqueous biphasic systems to deep eutectic solvents.” Russian Chemical Reviews, vol. 90, no. 9, Nov. 2020, pp. 1109-1141. https://rcr.colab.ws/publications/10.1070/RCR5007.
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Keywords

aqueous biphasic systems
combined solvents
eutectic solvents
Green chemistry
ionic liquids
Liquid-liquid extraction
low-melting combined solvents
solvents

Abstract

The review is devoted to extraction solvents of new generation, so called combined solvents, which include ionic liquids, aqueous biphasic systems and eutectic solvents. Most of modern combined solvents are based on organic ionic components. These solvents are associated with high expectations as they are able to provide the environmental safety and green character of extraction, which are priority tasks for the development of chemistry and chemical engineering. For all classes, an overview and a brief history of research are presented; details of structure and properties are discussed; various extraction systems are compared; and typical examples of extraction of metal ions and organic compounds are given. The lack of uniform terminology and difficulties in interpreting the behaviour of some systems, especially eutectic solvents, are outlined. The advantages and drawbacks of new generation extraction solvents and relevant research tasks are summarized.

The bibliography includes 408 references.

Funders

Russian Foundation for Basic Research
19-13-50261

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