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Hydrogen energy: development prospects and materials

Sergey Petrovich Filippov 1
Sergey Petrovich Filippov
, 
Andrei Borisovich Yaroslavtsev 2
Andrei Borisovich Yaroslavtsev
1 Energy Research Insnitute of the Russian Academy of Sciences, Moscow
2 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
10.1070/RCR5014
Published 30 November 2020
Review , RCR5014, Volume 90, Issue 6, 627-643
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Filippov S. P., Yaroslavtsev A. B. Hydrogen energy: development prospects and materials // Russian Chemical Reviews. 2020. Vol. 90. No. 6. pp. 627-643.
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Filippov S. P., Yaroslavtsev A. B. Hydrogen energy: development prospects and materials // Russian Chemical Reviews. 2020. Vol. 90. No. 6. pp. 627-643.
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TY - JOUR
DO - 10.1070/RCR5014
UR - https://rcr.colab.ws/publications/10.1070/RCR5014
TI - Hydrogen energy: development prospects and materials
T2 - Russian Chemical Reviews
AU - Filippov, Sergey Petrovich
AU - Yaroslavtsev, Andrei Borisovich
PY - 2020
DA - 2020/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 627-643
IS - 6
VL - 90
ER -
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@article{2020_Filippov,
author = {Sergey Petrovich Filippov and Andrei Borisovich Yaroslavtsev},
title = {Hydrogen energy: development prospects and materials},
journal = {Russian Chemical Reviews},
year = {2020},
volume = {90},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR5014},
number = {6},
pages = {627--643},
doi = {10.1070/RCR5014}
}
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Filippov, Sergey Petrovich, and Andrei Borisovich Yaroslavtsev. “Hydrogen energy: development prospects and materials.” Russian Chemical Reviews, vol. 90, no. 6, Nov. 2020, pp. 627-643. https://rcr.colab.ws/publications/10.1070/RCR5014.
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Keywords

electrocatalysts
fuel cells
hydrogen
hydrogen energy
hydrogen production
hydrogen purification
Hydrogen storage
membranes
partial oxidation
steam reforming

Abstract

The review addresses the prospects of global hydrogen energy development. Particular attention is given to the design of materials for sustainable hydrogen energy applications, including hydrogen production, purification, storage, and conversion to energy. The review highlights the key role of oxide-supported metal or alloy nanoparticles as catalysts in the hydrogen production \textit{via} the conversion of natural gas or alcohols. An alternative approach is the pyrolysis of hydrocarbons giving hydrogen and carbon. The direct production of high-purity hydrogen can be performed using electrolysis or membrane catalysis. Apart from conventional hydrogen storage methods such as the compression and liquefaction, the hydrogen alloy absorption and chemical conversion to liquid carriers (ammonia and toluene cycles) are considered. Fuel cells, containing catalysts and proton-conducting membranes as the key components, are used for hydrogen energy generation. Binary platinum alloys or core--shell structures supported on carbon or oxides can be employed to facilitate the oxygen electroreduction and CO electrooxidation in low-temperature fuel cells. High conductivity and selectivity are provided by perfluorinated sulfonic acid membranes. The high cost of the latter materials dictates the development of alternative membrane materials. A crucial issue in high-temperature fuel cells is the necessity of reducing the operating temperature and ohmic losses. This problem can be solved by designing thin-film materials and replacing oxygen-conducting ceramic membranes by proton-conducting membranes.

The bibliography includes 290 references.

Funders

Ministry of Education and Science of the Russian Federation

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