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Epoxides: methods of synthesis, reactivity, practical significance

Vera Leonidovna Mamedova 1
Vera Leonidovna Mamedova
, 
Gulnaz Zufarovna Khikmatova 1
Gulnaz Zufarovna Khikmatova
, 
Dmitry Eduardovich Korshin 1
Dmitry Eduardovich Korshin
, 
Sevil Vakhid kyzy Mamedova 2
Sevil Vakhid kyzy Mamedova
, 
Elena Leonidovna Gavrilova 2
Elena Leonidovna Gavrilova
, 
Vakhid Abdulla-ogly Mamedov 1
Vakhid Abdulla-ogly Mamedov
1 A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences
2 Kazan National Research Technological University
Published 30 November 2021
Communication , Volume 91, Issue 11
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Mamedova V. L. et al. Epoxides: methods of synthesis, reactivity, practical significance // Russian Chemical Reviews. 2022. Vol. 91. No. 11.
GOST all authors (up to 50)
Mamedova V. L., Khikmatova G. Z., Korshin D. E., Mamedova S. V. K., Gavrilova E. L., Mamedov V. A. Epoxides: methods of synthesis, reactivity, practical significance // Russian Chemical Reviews. 2022. Vol. 91. No. 11.
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TY - JOUR
DO - 10.57634/RCR5049
UR - https://rcr.colab.ws/publications/10.57634/RCR5049
TI - Epoxides: methods of synthesis, reactivity, practical significance
T2 - Russian Chemical Reviews
AU - Mamedova, Vera Leonidovna
AU - Khikmatova, Gulnaz Zufarovna
AU - Korshin, Dmitry Eduardovich
AU - Mamedova, Sevil Vakhid kyzy
AU - Gavrilova, Elena Leonidovna
AU - Mamedov, Vakhid Abdulla-ogly
PY - 2022
DA - 2021/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
IS - 11
VL - 91
ER -
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Cite this
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@article{2022_Mamedova,
author = {Vera Leonidovna Mamedova and Gulnaz Zufarovna Khikmatova and Dmitry Eduardovich Korshin and Sevil Vakhid kyzy Mamedova and Elena Leonidovna Gavrilova and Vakhid Abdulla-ogly Mamedov},
title = {Epoxides: methods of synthesis, reactivity, practical significance},
journal = {Russian Chemical Reviews},
year = {2022},
volume = {91},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.57634/RCR5049},
number = {11},
doi = {10.57634/RCR5049}
}

Keywords

carbonylation
carboxylation
chemical properties
drugs
epoxides
heterocyclic compounds
multicomponent reactions
natural compounds
polymerization
rearrangements
synthesis

Abstract

This review systematically summarizes recent literature data on the chemistry of epoxides published from 2010 to 2021 and, in part, in 2022. Epoxides are an important class of compounds, which are valuable building blocks in the design of new structures serving as the basis for many practically important compounds. Epoxy derivatives have long attracted the attention of synthetic chemists, as confirmed by a number of name reactions associated with their synthesis. The review describes methods for the synthesis of epoxy compounds, including both improved classical and new approaches, considers chemical reactions involving epoxides, discusses the practical significance of such compounds in relation to the synthesis of natural products, drugs and polymer structures and the CO and CO2 utilization. Much attention is paid to the issues of asymmetric synthesis, which enable one to get a general idea on the current trends in the chemistry of epoxides. The most unexpected rearrangements of functionalized epoxides are considered and the role of epoxy compounds in the synthesis of various carbo- and heterocyclic systems is discussed.
The bibliography includes 555 references.

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