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Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR)

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10.59761/RCR5085
2023-06-28 , Review , RCR5085, Volume 92, Issue 6
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Anton V. Kuzmin, Bagrat A. Shainyan Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR) // Russian Chemical Reviews. 2023. Vol. 92. No. 6. RCR5085
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Anton V. Kuzmin, Bagrat A. Shainyan Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR) // Russian Chemical Reviews. 2023. Vol. 92. No. 6. RCR5085
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TY - GENERIC
DO - 10.59761/RCR5085
UR - https://rcr.colab.ws/publications/10.59761/RCR5085
TI - Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR)
T2 - Russian Chemical Reviews
PB - Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
AU - Kuzmin, Anton V.
AU - Shainyan, Bagrat A.
PY - 2023
SP - RCR5085
IS - 6
VL - 92
ER -
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@misc{2023_Kuzmin,
author = {Anton V. Kuzmin and Bagrat A. Shainyan},
title = {Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR)},
month = {jun},
year = {2023}
}
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Kuzmin, Anton V., and Bagrat A. Shainyan. “Mechanisms of catalytic electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR).” Russian Chemical Reviews, vol. 92, no. 6, Jun. 2023, p. RCR5085. https://rcr.colab.ws/publications/10.59761/RCR5085.

Keywords

CO2RR
Electrocatalytic reduction
mechanisms
ORR
quantum chemical calculations

Abstract

The review covers the electrochemical reactions of oxygen reduction (ORR) and carbon dioxide reduction (CO2RR) with a focus on mechanisms, structure of intermediates, and thermodynamics of reactions. The ORR on metal,heteroatom-codoped nanocarbon substrates as catalysts is a promising source of pure electrical energy. CO2RR, being a synthetic analogue of the photosynthesis reaction, has great potential for the generation of partial or complete reduction products. Theoretical insights into the mechanism and kinetics of CO2RR are just being developed, so the systematization of advances and emerging issues is a necessary step for further progress.

The bibliography includes 242 references.