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Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds

E S Shcherbakova 1
E S Shcherbakova
, 
Inessa Pavlovna Gol'dshtein 1
Inessa Pavlovna Gol'dshtein
, 
Elena Nikolaevna Gur'yanova 1
Elena Nikolaevna Gur'yanova
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1978v047n12ABEH002297
Published 30 November 1977
Communication , Volume 47, Issue 12, 1133-1148
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Shcherbakova E. S., Gol'dshtein I. P., Gur'yanova E. N. Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds // Russian Chemical Reviews. 1978. Vol. 47. No. 12. pp. 1133-1148.
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Shcherbakova E. S., Gol'dshtein I. P., Gur'yanova E. N. Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds // Russian Chemical Reviews. 1978. Vol. 47. No. 12. pp. 1133-1148.
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TY - JOUR
DO - 10.1070/RC1978v047n12ABEH002297
UR - https://rcr.colab.ws/publications/10.1070/RC1978v047n12ABEH002297
TI - Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds
T2 - Russian Chemical Reviews
AU - Shcherbakova, E S
AU - Gol'dshtein, Inessa Pavlovna
AU - Gur'yanova, Elena Nikolaevna
PY - 1978
DA - 1977/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1133-1148
IS - 12
VL - 47
ER -
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@article{1978_Shcherbakova,
author = {E S Shcherbakova and Inessa Pavlovna Gol'dshtein and Elena Nikolaevna Gur'yanova},
title = {Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds},
journal = {Russian Chemical Reviews},
year = {1978},
volume = {47},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1978v047n12ABEH002297},
number = {12},
pages = {1133--1148},
doi = {10.1070/RC1978v047n12ABEH002297}
}
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Shcherbakova, E. S., et al. “Methods of Mathematical Treatment of the Results of Physicochemical Studies on Complex Compounds.” Russian Chemical Reviews, vol. 47, no. 12, Nov. 1978, pp. 1133-1148. https://rcr.colab.ws/publications/10.1070/RC1978v047n12ABEH002297.
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Abstract

The general principles of the determination of the equilibrium constants and the physicochemical parameters of complexes under the conditions of their dissociation are examined. The possibilities of approximate computational methods and direct analytical procedures for the solution of systems of the corresponding equations are analysed. Various methods involving the simultaneous determination of the equilibrium constants and physicochemical parameters of complexes, based on the statistical principle of maximum probability, are compared. The ways of the most rational employment of computer techniques in the study of involved complex-formation reactions by various physical methods are discussed.
The bibliography includes 226 references.

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