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The chemistry of the compound semiconductor-intrinsic insulator interface

Nikolai Nikolaevich Berchenko 1
Nikolai Nikolaevich Berchenko
, 
Yu V Medvedev 1
Yu V Medvedev
1 State University "L'vovskaya Politekhnika"
Published 30 November 1993
Communication , Volume 63, Issue 8, 623-639
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Berchenko N. N., Medvedev Yu. V. The chemistry of the compound semiconductor-intrinsic insulator interface // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 623-639.
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Berchenko N. N., Medvedev Yu. V. The chemistry of the compound semiconductor-intrinsic insulator interface // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 623-639.
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TY - JOUR
DO - 10.1070/RC1994v063n08ABEH000108
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000108
TI - The chemistry of the compound semiconductor-intrinsic insulator interface
T2 - Russian Chemical Reviews
AU - Berchenko, Nikolai Nikolaevich
AU - Medvedev, Yu V
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 623-639
IS - 8
VL - 63
ER -
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@article{1994_Berchenko,
author = {Nikolai Nikolaevich Berchenko and Yu V Medvedev},
title = {The chemistry of the compound semiconductor-intrinsic insulator interface},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000108},
number = {8},
pages = {623--639},
doi = {10.1070/RC1994v063n08ABEH000108}
}
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Berchenko, Nikolai Nikolaevich, and Yu V Medvedev. “The chemistry of the compound semiconductor-intrinsic insulator interface.” Russian Chemical Reviews, vol. 63, no. 8, Nov. 1994, pp. 623-639. https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000108.
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Abstract

Processes leading to the growth of intrinsic insulators (oxides, sulfides, and fluorides) on the surfaces of semiconductors of the III–V, II–VI, and IV–VI groups as well as their solid solutions are analysed with the aid of classical thermodynamics. Their phase compositions, found from the equilibrium phase diagram, are compared with the compositions found as a result of experimental studies of the semiconductor-insulator interface. It is shown that there is a relation between the characteristic features of the equilibrium phase diagram (in particular the segregation of a metal or nonmetal at the interface), the type of intrinsic lattice defects, and the electrophisical properties of the interface. The possible ways of creating an ideal compound semiconductor-insulator interface are considered. The bibliography includes 171 references.

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