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Methods of calculation of the critical conversion in the formation of network polymers

Vadim Isaakovich Irzhak 1
Vadim Isaakovich Irzhak
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2004v073n03ABEH000881
Published 30 November 2003
Communication , Volume 73, Issue 3, 251-265
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Irzhak V. I. Methods of calculation of the critical conversion in the formation of network polymers // Russian Chemical Reviews. 2004. Vol. 73. No. 3. pp. 251-265.
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Irzhak V. I. Methods of calculation of the critical conversion in the formation of network polymers // Russian Chemical Reviews. 2004. Vol. 73. No. 3. pp. 251-265.
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TY - JOUR
DO - 10.1070/RC2004v073n03ABEH000881
UR - https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000881
TI - Methods of calculation of the critical conversion in the formation of network polymers
T2 - Russian Chemical Reviews
AU - Irzhak, Vadim Isaakovich
PY - 2004
DA - 2003/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 251-265
IS - 3
VL - 73
ER -
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@article{2004_Irzhak,
author = {Vadim Isaakovich Irzhak},
title = {Methods of calculation of the critical conversion in the formation of network polymers},
journal = {Russian Chemical Reviews},
year = {2004},
volume = {73},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000881},
number = {3},
pages = {251--265},
doi = {10.1070/RC2004v073n03ABEH000881}
}
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Irzhak, Vadim Isaakovich. “Methods of calculation of the critical conversion in the formation of network polymers.” Russian Chemical Reviews, vol. 73, no. 3, Nov. 2004, pp. 251-265. https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000881.
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Abstract

Mathematical methods of calculation of the critical conversion (gel point) in the formation of cross-linked polymers by polycondensation, cross-linking of macromolecules and three-dimensional polymerisation are considered. The results obtained using the statistical approach ('ideal' polycondensation), the concept of bond blocks (the 'non-ideal' or 'non-statistical' polycondensation) and kinetic calculations that allowed the determination of the gel point in three-dimensional polymerisation processes are discussed.

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