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Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems

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1 Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow
2 Institute of Cristallography Russian Academy of Sciences, Moscow
10.1070/RC2012v081n01ABEH004207
Published 30 November 2011
Communication , Volume 81, Issue 1, 1-20
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Fedorov P. P., Buchinskaya I. I. Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems // Russian Chemical Reviews. 2012. Vol. 81. No. 1. pp. 1-20.
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Fedorov P. P., Buchinskaya I. I. Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems // Russian Chemical Reviews. 2012. Vol. 81. No. 1. pp. 1-20.
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TY - JOUR
DO - 10.1070/RC2012v081n01ABEH004207
UR - https://rcr.colab.ws/publications/10.1070/RC2012v081n01ABEH004207
TI - Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems
T2 - Russian Chemical Reviews
AU - Fedorov, Pavel Pavlovich
AU - Buchinskaya, Irina Igorevna
PY - 2012
DA - 2011/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-20
IS - 1
VL - 81
ER -
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@article{2012_Fedorov,
author = {Pavel Pavlovich Fedorov and Irina Igorevna Buchinskaya},
title = {Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems},
journal = {Russian Chemical Reviews},
year = {2012},
volume = {81},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2012v081n01ABEH004207},
number = {1},
pages = {1--20},
doi = {10.1070/RC2012v081n01ABEH004207}
}
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Fedorov, Pavel Pavlovich, and Irina Igorevna Buchinskaya. “Spatial inhomogeneity in crystalline materials and saddle-type congruent melting points in ternary systems.” Russian Chemical Reviews, vol. 81, no. 1, Nov. 2012, pp. 1-20. https://rcr.colab.ws/publications/10.1070/RC2012v081n01ABEH004207.
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Abstract

Solidification of multicomponent melts to solid solutions is considered in terms of thermodynamic topological analysis. The use of phase portraits of systems for finding congruent melting points (invariant points) is discussed. Methods for predicting the existence of invariant points in ternary systems are considered. An example analysis is presented for two series of fluoride systems (CaF2–SrF2–RF3 and SrF2–BaF2–RF3, where R are rare-earth elements). The stability of melt crystallization in the vicinity of congruent melting singular points of solid solutions is discussed. The bibliography includes 104 references.

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