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Dispersion forces in nanoscience

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Elena Nikolaevna Brodskaya 1
Elena Nikolaevna Brodskaya
1 Institute of Chemistry, St. Petersburg State University
10.1070/RCR4879
Published 30 November 2018
Review , RCRR4879, Volume 88, Issue 8, 837-874
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Rusanov A. I., Brodskaya E. N. Dispersion forces in nanoscience // Russian Chemical Reviews. 2018. Vol. 88. No. 8. pp. 837-874.
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Rusanov A. I., Brodskaya E. N. Dispersion forces in nanoscience // Russian Chemical Reviews. 2018. Vol. 88. No. 8. pp. 837-874.
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TY - JOUR
DO - 10.1070/RCR4879
UR - https://rcr.colab.ws/publications/10.1070/RCR4879
TI - Dispersion forces in nanoscience
T2 - Russian Chemical Reviews
AU - Rusanov, Anatoly Ivanovich
AU - Brodskaya, Elena Nikolaevna
PY - 2018
DA - 2018/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 837-874
IS - 8
VL - 88
ER -
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@article{2018_Rusanov,
author = {Anatoly Ivanovich Rusanov and Elena Nikolaevna Brodskaya},
title = {Dispersion forces in nanoscience},
journal = {Russian Chemical Reviews},
year = {2018},
volume = {88},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4879},
number = {8},
pages = {837--874},
doi = {10.1070/RCR4879}
}
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Rusanov, Anatoly Ivanovich, and Elena Nikolaevna Brodskaya. “Dispersion forces in nanoscience.” Russian Chemical Reviews, vol. 88, no. 8, Nov. 2018, pp. 837-874. https://rcr.colab.ws/publications/10.1070/RCR4879.
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Abstract

The 21st century was marked by a new outbreak of interest in dispersion forces in nanoscale systems. However, now the consideration is conducted at a different level. Whereas earlier the main object of study was infinite plane-parallel films, now it is a question of calculations for systems of a more complex configuration with non-parallel and finite surfaces of various shapes. On the other hand, it is not the average interaction force that is estimated, but the detailed mechanical state of the interacting bodies, for which statistical mechanics and the Irving--Kirkwood stress tensor are involved. This review summarizes the theoretical studies of plane-parallel, but finite-area films, wedge-shaped films, systems with spherical, cylindrical, and conical surfaces. Particular consideration is given to interactions involving nanoparticles. Spheroidal particles, rod-like and disc-shaped particles are analyzed. The shape factor of the interaction of particles with a flat surface is estimated. The calculation of the contribution of dispersion forces to surface, line and point tension is explained. Among the latest news is the calculation (brought to numbers) of the contribution of dispersion forces to the graphene point energy.

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